5-[(4-Methyl-phen-yl)sulfon-yl]-1-phenyl-thio-pyrano[4,3-]indole-3(5)-thione di-chloro-methane monosolvate.

Rhodium-catalyzed [2+2+2] cyclo-addition of carbon di-sulfide to ,-dialkynyl-tosyl-anilines gives two isomeric indolo-thio-pyran-thio-nes, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent mol-ecule of di-chloro-methane in the asymmetric unit, CHNOS·CHCl. In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent mol-ecules fill the space between the strands.

Microwave Signature of Topological Andreev level Crossings in a Bismuth-based Josephson Junction.

Demonstrating the topological protection of Andreev states in Josephson junctions is an experimental challenge. In particular the telltale 4π periodicity expected for the current phase relation has remained elusive, because of fast parity breaking processes. It was predicted that low temperature ac susceptibility measurements could reveal the topological protection of quantum spin Hall edge states by probing their low energy Andreev spectrum at finite frequency.

Weakly-coupled quasi-1D helical modes in disordered 3D topological insulator quantum wires.

Disorder remains a key limitation in the search for robust signatures of topological superconductivity in condensed matter. Whereas clean semiconducting quantum wires gave promising results discussed in terms of Majorana bound states, disorder makes the interpretation more complex. Quantum wires of 3D topological insulators offer a serious alternative due to their perfectly-transmitted mode.

Enhanced Mobility of Spin-Helical Dirac Fermions in Disordered 3D Topological Insulators.

The transport length l and the mean free path l are determined for bulk and surface states in a BiSe nanoribbon by quantum transport and transconductance measurements. We show that the anisotropic scattering of spin-helical Dirac fermions results in a strong enhancement of l (≈ 200 nm) and of the related mobility μ (≈ 4000 cm V s), which confirms theoretical predictions.1 Despite strong disorder, the long-range nature of the scattering potential gives a large ratio l/l ≈ 8, likely limited by bulk/surface coupling.