The experiences of trans (binary and non-binary) people accessing emergency department care in Australia: A grounded theory study.

Background: This study aimed to explore the experiences of trans (binary and non-binary) people accessing emergency department care in Australia.

Method: This qualitative descriptive study utilised a grounded theory approach. Seven people who identified as trans were recruited through social media and trans support groups.

Investigation of Per- and Poly-fluoroalkyl Substance (PFAS) Adsorption on Zerovalent Iron (Fe).

In this study, dispersion-corrected density functional theory (DFT) calculations were employed to investigate the adsorption of per- and poly-fluoroalkyl substances (PFAS) onto zerovalent iron (Fe). The main objective of this investigation was to shed light on the adsorption properties, including adsorption energies, geometries, and charge transfer mechanisms, for four PFAS molecules, namely, perfluorooctanesulfonic acid (PFOS), perfluorobutanesulfonic acid (PFBS), perfluorooctanoic acid (PFOA), and perfluorobutanoic acid (PFBA), on the most thermodynamically accessible Fe surface facets. Additionally, the DFT investigation examined the role of PFAS chain length, functional group, protonation/deprotonation state, and solvation in water in their adsorption to Fe.

Novel Conductive and Redox-Active Molecularly Imprinted Polymer for Direct Quantification of Perfluorooctanoic Acid.

This study developed a novel molecularly imprinted polymer (MIP) that is both conductive and redox-active for directly quantifying perfluorooctanoic acid (PFOA) electrochemically. We synthesized the monomer 3,4-ethylenedioxythiophene-2,2,6,6-tetramethylpiperidinyloxy (EDOT-TEMPO) for electropolymerization on a glassy carbon electrode using PFOA as a template, which was abbreviated as PEDOT-TEMPO-MIP. The redox-active MIP eliminated the need for external redox probes.

Adsorption of per- and poly-fluoroalkyl substances (PFAS) on Ni: A DFT investigation.

Electrocatalytic destruction of per- and polyfluoroalkyl substances (PFAS) is an emerging approach for treatment of PFAS-contaminated water. In this study, a systematic ab initio investigation of PFAS adsorption on Ni, a widely used electrocatalyst, was conducted by means of dispersion-corrected Density Functional Theory (DFT) calculations. The objective of this investigation was to elucidate the adsorption characteristics and charge transfer mechanisms of different PFAS molecules on Ni surfaces.

Pretreatment and Acquired Drug Resistance in Children With Human Immunodeficiency Virus Type 1 in Jos, Nigeria.

We determined pretreatment and acquired human immunodeficiency virus (HIV) drug resistance among children with HIV type 1 (HIV-1) in Jos, Nigeria. The majority (71%) of those who failed first-line antiretroviral therapy were on a nevirapine-containing regimen. The prevalence of pretreatment (48%) and acquired (76%) HIV drug resistance mutations was high in our study.