Publications by authors named "B A Haruna"

Transition metal chalcogenides (TMCs) hold great potential for sodium-ion batteries (SIBs) owing to their multielectron conversion reactions, yet face challenges of poor intrinsic conductivity, sluggish diffusion kinetics, severe phase transitions, and structural collapse during cycling. Herein, a self-templating strategy is proposed for the synthesis of a class of metal cobalt-doped NiSe nanoparticles confined within three-dimensional (3D) N-doped macroporous carbon matrix nanohybrids (Co-NiSe/NMC). The cation defect engineering within the developed Co-NiSe and 3D N-doped carbon plays a crucial role in enhancing intrinsic conductivity, reinforcing structural stability, and reducing the barrier to sodium ion diffusion, which are verified by a series of electrochemical kinetic analyses and density functional theory calculations.

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Nickel-based sulfides are considered promising materials for sodium-ion batteries (SIBs) anodes due to their abundant resources and attractive theoretical capacity. However, their application is limited by slow diffusion kinetics and severe volume changes during cycling. Herein, we demonstrate a facile strategy for the synthesis of nitrogen-doped reduced graphene oxide (N-rGO) wrapped NiS nanocrystals composites (NiS-N-rGO-700 °C) through the cubic NiS precursor under high temperature (700 ℃).

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Article Synopsis
  • - The study introduces a new method for creating benzo[]phosphole oxides by using a reaction that combines alkynylphosphine oxides with common cycloalkanes, alcohols, and ethers.
  • - This process utilizes visible light and is environmentally friendly, operating without a photocatalyst and at room temperature.
  • - The reaction is mild and doesn't require metals or bases, allowing for the efficient construction of diverse chemical structures through sequential C-H functionalization.
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The milestone in polio eradication program is to protect effectively children aged 0-5 years against the three serotypes of poliovirus. It became necessary to measure the level of neutralizing antibodies to the three poliovirus types in an endemic State in Nigeria. Neutralizing antibodies to the poliovirus types among children aged 0-5 years was estimated using micro neutralization assay.

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