Publications by authors named "Aziz U Rehman"

The severe acute respiratory syndrome coronavirus-2 (SARS-CoV-2), causes acute coronavirus disease-19 (COVID-19) that has emerged on a pandemic level. Coronaviruses are well-known to have a negative impact on the lungs and cardiovascular system. SARS-CoV-2 induces a cytokine storm that primarily targets the lungs, causing widespread clinical disorders, including COVID-19.

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The aim of the present research was the efficient degradation of industrial textile wastewater dyes using a very active cloned laccase enzyme. For this purpose, potent laccase-producing bacteria were isolated from soil samples collected from wastewater-replenished textile sites in Punjab, Pakistan. The laccase gene from locally isolated strain LI-81, identified as , was cloned into vector pET21a, which was further transformed into BL21 codon plus.

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Article Synopsis
  • MXenes are advanced 2D materials known for their electrical conductivity and high surface area, which can be combined with metal-organic frameworks (MOFs) to enhance stability and conductivity issues often found in conventional MOFs.
  • The review discusses various methods for synthesizing MXene/MOF composites, such as hydrothermal and solvothermal methods, highlighting their potential applications in catalytic water splitting and wastewater treatment.
  • The integration of MXenes with MOFs not only improves conductivity and stability but also introduces unique features, positioning these composites as promising solutions for environmental challenges, while also addressing current challenges and future opportunities in the field.
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Objective: This study aimed to investigate the prevalence of paratuberculosis in cattle and buffaloes at twelve public dairy farms in Punjab, Pakistan.

Methods: A total of 2,181 more than two-year-old animals (1,242 cattle and 939 buffaloes) were tested by avian tuberculin, i.e.

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The primary objective of this research is to develop a mathematical model, analyze the dynamic occurrence of thermal shock and exploration of how thermal memory with moving line impact of heat transfer within biological tissues. An extended version of the Pennes equation as its foundational framework, a new fractional modelling approach called the Prabhakar fractional operator to investigate and a novel time-fractional interpretation of Fourier's law that incorporates its historical behaviour. This fractional operator has multi parameter generalized Mittag-Leffler kernel.

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Article Synopsis
  • - Enzootic bovine leucosis, caused by the bovine leukaemia virus (BLV), leads to significant economic losses in the dairy industry due to issues like reduced milk production and reproduction problems.
  • - A study in Punjab, Pakistan, tested 384 buffalo samples for BLV using ELISA and found an 18.2% seroprevalence, with age showing a significant link to higher infection rates, alongside milk yield and pregnancy, while factors like sex and health status showed no significant connection.
  • - The study also indicated biochemical changes in seropositive buffalo, such as decreased liver enzymes and oxidative stress markers, suggesting that BLV is prevalent in the region and highlighting the need for further
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Respecting the basic need of clean and safe water on earth for every individual, it is necessary to take auspicious steps for waste-water treatment. Recently, metal-organic frameworks (MOFs) are considered as promising material because of their intrinsic features including the porosity and high surface area. Further, structural tunability of MOFs by following the principles of reticular chemistry, the MOFs can be functionalized for the high adsorption performance as well as adsorptive removal of target materials.

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  • The study measured aflatoxin M (AFM) levels in milk from Holstein Friesian cows and found that 69.4% exceeded the safe limit, particularly higher in winter (82.5%) than in summer (53.1%).
  • The presence of AFM negatively impacted milk quality, reducing fat, solids-not-fat, and protein levels in affected cows.
  • Feeding a clay-based toxin binder significantly reduced AFM levels by 53.6% over a week and improved milk quality, suggesting a potential solution to AFM contamination in Pakistan's dairy production.
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  • * A study in Punjab, Pakistan, assessed the prevalence of ESBL-producing bacteria in wild aquatic birds and chickens by analyzing 280 samples, confirming 34.64% were ESBL producers, with the highest rates found in chickens (44.28%).
  • * Researchers identified five types of ESBL-producing bacteria using genetic sequencing and found a range of ESBL genes present, including genetic combinations in a minority of isolates, indicating genetic diversity among the bacteria.
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Introduction: Animal tuberculosis is an infectious, chronic, granulomatous, and debilitating disease affecting animals as well as humans. However, in recent decades, there have been many endemic geographic localities where animal tuberculosis has been identified in wildlife reservoirs, limiting the eradication program in cattle. This study aimed to identify animal tuberculosis in captive zoo animals in Pakistan.

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Abortion is one of the leading causes of economic losses in the livestock industry worldwide. , , and spp. are the leading cause of late fetal loss in small ruminants.

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Triazole-based acetamides serve as important scaffolds for various pharmacologically active drugs. In the present work, structural hybrids of 1,2,4-triazole and acetamides were furnished by chemically modifying 2-(4-isobutylphenyl) propanoic acid (). Target compounds were produced in considerable yields (70-76%) by coupling the triazole of compound 1 with different electrophiles under different reaction conditions.

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The increasing incidence of extended-spectrum β-lactamase (ESBL)-producing (.) in backyard chicken farming in Pakistan is of serious concern. This study aimed to assess the prevalence, antimicrobial resistance patterns and risk factors associated with ESBL avian pathogenic (APEC) isolated from backyard chickens in the Jhang district, Punjab, Pakistan.

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An array of 1,3,4-oxadiazole hybrids, , structurally intriguing cores with potential in natural product synthesis and drug discovery, have been synthesized using innovative comparable conventional and microwave-assisted protocols. The synthesis was performed by the reaction of secondary amine-based acetamides, , as the electrophile and piperidine-based oxadiazoles as the nucleophile, , under the metal-free reaction conditions. High yield in minimum time with highest purity was obtained by the microwave-irradiated method instead of the conventional one.

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Vaccination/immunization plays a key role in maintaining the optimum health of humans and animals where the prevalence of disease is high and treatment becomes less effective [...

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Fifth generation (5G) is a recent wireless communication technology in mobile networks. The key parameters of 5G are enhanced coverage, ultra reliable low latency, high data rates, massive connectivity and better support to mobility. Enhanced coverage is one of the major issues in the 5G and beyond 5G networks, which will be affecting the overall system performance and end user experience.

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The hydrogen evolution reaction (HER) is a developing and promising technology to deliver clean energy using renewable sources. Presently, electrocatalytic water (HO) splitting is one of the low-cost, affordable, and reliable industrial-scale effective hydrogen (H) production methods. Nevertheless, the most active platinum (Pt) metal-based catalysts for the HER are subject to high cost and substandard stability.

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The present study reports the fish fauna of Gomal Zam Dam at three different sites from October 2018 to July 2019. The total sampled fish belong to 18 species, 15 genera, 5 families, and 4 orders. Fourteen species belong to family Cyprinidae, which was the most abundant, while one species belong to each family Mastacembelidae, Channidae, Siluridae, and Sisoridae.

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The rapid industrialization of the world is disparagingly manipulating our environment and natural ecosystem. The researchers are taking keen interest to invent novel material as photocatalyst for non-degradable organic pollutants. Solar energy-driven practices employing semiconductors are a novel approach towards wastewater remediation.

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The aim of this article is to investigate the exact solution by using a new approach for the thermal transport phenomena of second grade fluid flow under the impact of MHD along with exponential heating as well as Darcy's law. The phenomenon has been expressed in terms of partial differential equations, then transformed the governing equations in non-dimentional form. For the sake of better rheology of second grade fluid, developed a fractional model by applying the new definition of Constant Proportional-Caputo hybrid derivative (CPC), Atangana Baleanu in Caputo sense (ABC) and Caputo Fabrizio (CF) fractional derivative operators that describe the generalized memory effects.

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This study presents the design and synthetic pathway of unsymmetric ligands based on pyridine-pyrazolate scaffold with Donor-Acceptor (D-A) molecular arrays and their boron complexes to achieve a large Stokes shift. Intermolecular charge transfer (ICT) triggered by the uneven molecular charge distribution from electronically dense pyrazolate (donor) part of the ligands to electron-deficient boron centre (acceptor) resulted in a mega Stokes shift up to 263 nm for selected compounds while retaining the characteristic quantum efficiency and chemical stability. The photophysical properties of derivatization of pyrazolate group in the pyridine-pyrazolate scaffold of diaryl boron complexes were explored based on UV-Visible, steady-state and time-resolved fluorescence spectroscopy.

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In the current study, the application of fluorescence spectroscopy along with the advanced statistical technique and confocal microscopy was investigated for the early detection of stripe rust infection in wheat grown under field conditions. The indigenously developed Fluorosensor fitted with LED, emitting monochromatic light was used that covered comparatively larger leaf area for recording fluorescence data thus presenting more reliable current status of the leaf. The examined leaf samples covered the entire range of stripe rust disease infection from no visible symptoms to the complete disease prevalence.

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The design of conductive, improved durable and selective anion exchange membranes (AEMs) for desalination application via electrodialysis (ED) process is critical for a more sustainable future. This work reports the design of a series of homogeneous trimethylphosphine (TMP)-functionalized anion exchange membranes (AEMs) for desalination application via electrodialysis (ED) process. Physico-chemical characterization and electrochemical performance of the trimethylphosphine-functionalized anion exchange membranes was conducted and the activity found to be tuned by varying the quantity of trimethylphosphine into the membrane architecture.

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