Low-loading Pd supported on FeO nanoparticles was synthesized. A common nanocatalyst system with previously reported synergistic enhancement of reactivity that is attributed to the electronic interactions between Pd and the FeO support. FeO-selective precoalescence overcoating with ZnO atomic layer deposition (ALD), using Zn(CHCH) and HO as precursors, dampens competitive hydrogenation reactivity at FeO-based sites.
View Article and Find Full Text PDFGalvanic exchange seeds the growth of Pt nanostructures on the Ni foam monolith. Subsequent atomic layer deposition of ultrathin AlO followed by annealing under air affords supported Pt catalysts with ultralow loading (0.020 ppm).
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