A Numerical Simulation Study of the Impact of Kesterites Hole Transport Materials in Quantum Dot-Sensitized Solar Cells Using SCAPS-1D.

Energy generation and storage are critical challenges for developing economies due to rising populations and limited access to clean energy resources. Fossil fuels, commonly used for energy production, are costly and contribute to environmental pollution through greenhouse gas emissions. Quantum dot-sensitized solar cells (QDSSCs) offer a promising alternative due to their stability, low cost, and high-power conversion efficiency (PCE) compared to other third-generation solar cells.

Hybrid porous material supported in a cellulose acetate polymeric membrane for the direct immersion thin-film microextraction of parabens in water.

A simple and sensitive direct immersion thin-film microextraction (DI-TFME) method based on MIL-101(Cr) modified with carbon nanofibers supported in cellulose acetate (CA-MIL-101(Cr)@CNFs) polymeric membrane was developed for the extraction and preconcentration of parabens in environmental water samples. A high-performance liquid chromatography-diode array detector (HPLC-DAD) was used for the determination and quantification of methylparaben (MP) and propylparaben (PP). The factors affecting the DI-TFME performance were investigated using central composite design (CCD).

Removal of methylene blue using MnO@rGO nanocomposite from textile wastewater: Isotherms, kinetics and thermodynamics studies.

In this study, the adsorptive removal of methylene blue dye, which is commonly used in textile industries, was investigated using the MnO@reduced graphene oxide (rGO) adsorbent. The sonication-assisted synthesis from rGO nanosheets and MnO nanoparticles resulted to the MnO@rGO nanocomposite with improved physicochemical properties. The characterization results showed the improved surface area, porous structure and adsorption sites from the nitrogen adsorption-desorption studies, improved morphology from the Scanning Electron Microscope (SEM) and Transmission Electron Microscope (TEM) and the improved crystal structure from X-ray powder diffraction (XRD).

From polyethylene waste bottles to UIO-66 (Zr) for preconcentration of steroid hormones from river water.

Metal-organic framework (UiO-66 (Zr) was synthesized using polyethylene terephthalate (PET) and used as an adsorbent for extraction and preconcentration of steroid hormones in river water. Polyethylene waste bottles were used as the source of polyethylene terephthalate (PET) ligands. The UIO-66(Zr), which the PET was made from recycled waste plastics, was used for the first time for the extraction and preconcentration of four different types of steroid hormones in river water samples.

Beta-Cyclodextrin-Decorated Magnetic Activated Carbon as a Sorbent for Extraction and Enrichment of Steroid Hormones (Estrone, β-Estradiol, Hydrocortisone and Progesterone) for Liquid Chromatographic Analysis.

A β-cyclodextrin-decorated magnetic activated carbon adsorbent was prepared and characterized using various analytical techniques (X-ray diffraction (XRD), scanning electron microscopy-electron diffraction spectroscopy (SEM-EDS) and transmission electron microscopy (TEM)), and the adsorbent was used in the development of a magnetic solid-phase microextraction (MSPE) method for the preconcentration of estrone, β-estradiol, hydrocortisone and progesterone in wastewater and river water samples. This method was optimized using the central composite design in order to determine the experimental parameters affecting the extraction procedure. The quantification of hormones was achieved using high-performance liquid chromatography equipped with a photodiode array detector (HPLC-DAD).

Application of Response Surface Methodology and Desirability Function in the Optimization of Adsorptive Remediation of Arsenic from Acid Mine Drainage Using Magnetic Nanocomposite: Equilibrium Studies and Application to Real Samples.

A magnetic multi-walled carbon nanotube/zeolite nanocomposite was applied for the adsorption and removal of arsenic ions in simulated and real acid mine drainage samples. The adsorption mechanism was investigated using two-parameter (Langmuir, Freundlich, Temkin) and three-parameter (Redlich-Peterson, and Sips) isotherm models. This was done in order to determine the characteristic parameters of the adsorptive removal process.

Adsorptive removal of lead from acid mine drainage using cobalt-methylimidazolate framework as an adsorbent: kinetics, isotherm, and regeneration.

In this work, cobalt-methylimidazolate framework has been used as an adsorbent in the removal of Pb(II) from acid mine drainage in adsorption batch system. X-ray diffraction, Fourier-transform infrared spectroscopy, Brunauer-Emmet-Teller and transmission electron microscope were used for structural, morphological, and surface characteristics of cobalt-methylimidazolate framework. The concentration of heavy metal ions in water samples was measured by inductively coupled plasma optical emission spectrometry.