From their first employment in the 1950s, acrylic emulsions have remained widely used as art material today. Although under certain deteriorating conditions they are very stable, if exposed to high humidity and atmospheric pollutant gases, their structural and chemical conformation is strongly affected. Dealing with the resulting surfactant migration, various cleaning treatments were considered over the years.
View Article and Find Full Text PDFSurface microstructures of bitumen are key sites in atmospheric photo-oxidation leading to changes in the mechanical properties and finally resulting in cracking and rutting of the material. Investigations at the nanoscale remain challenging. Conventional combination of optical microscopy and spectroscopy cannot resolve the submicrostructures due to the Abbe restriction.
View Article and Find Full Text PDFHolist Nurs Pract
April 2019
This study, which is based on the Stages of Change Model, aimed to develop a Web-based smoking cessation program and to evaluate its effectiveness. An interventional study with 1 group was conducted with college students from Afyon Kocatepe University. First, the Web-Based Smoking Cessation Program was set up (www.
View Article and Find Full Text PDFBackground/aim: This study was conducted to determine the effect of transtheoretical model (TTM)-based individual counseling, training, and a 6-month follow-up on smoking cessation in adult women.
Materials And Methods: We carried out this randomized controlled trial in Konya, Turkey. Female subjects were randomly assigned into groups in a 1:1 ratio using block randomization, block size 3 × 3, divided by stages (precontemplation, contemplation, and preparation) and age (20-29, 30-39, and 40-49 years).
Monatsh Chem
September 2015
Abstract: Mixed-metal oxo clusters CuTiO(OOCR) (OOCR = methacrylate, propionate) were obtained by reaction of titanium alkoxides and copper carboxylates with propionic or methacrylic acid.
View Article and Find Full Text PDFThe mixed-metal oxo clusters FeTiO(OPr)(OMc) (OMc = methacrylate), ZnTiO(OPr)(OMc), CdTiO(OAc)(OMc)(HOPr), [CaTiO(OAc)(OMc)] , and [SrTiO(OMc)(HOMc)] were obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition TiO(OR)(OOCR'). The Ca and Sr derivatives consist of chains of condensed clusters.
View Article and Find Full Text PDFReaction of Zr(O(n)Bu)4 and silver acetate with methacrylic acid afforded a mixed-metal cluster with a Ag2Zr8O6 core and both methacrylate and 2-hydroxy-2-methylpropionate ligands.
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