Spectroscopic studies on the inclusion complex of 2-naphthol-6-sulfonate with beta-cyclodextrin.

The photophysical properties of 2-naphthol-6-sulfonate (2-NOH-6-S) in various solvents and in aqueous beta-cyclodextrin solution have been investigated. The fluorescence quantum yields in non-aqueous solvents are approximately 0.20+/-0.

Inclusion complex of 2-naphthylamine-6-sulfonate with beta-cyclodextrin: intramolecular charge transfer versus hydrogen bonding effects.

The photophysical characteristics of the ground and excited states of 2-naphthylamine-6-sulfonate (2-NA-6-S) were investigated in different solvents and in beta-cyclodextrin (beta-CD). The spectral shifts are well correlated with Kamlet-Taft relationship. Multiple linear regression analysis indicated that both non-specific dipolar interaction and specific hydrogen bonding interactions play competitive roles in determining the position of the absorption maximum, while the dipolar interaction is the dominating parameter in determining the emission maximum.

Spectrophotometric determination of manganese by using redox reaction of tris(2,2'-bipyridine)osmium(II) with Mn7+.

This paper reports on the analytical application of the oxidation reaction of [Os(bpy)3]2+ by Mn7+ (MnO4-). The present study developed a very simple, sensitive and selective spectrophotometric method for the determination of manganese in an acidic medium. Three analytical wavelengths were employed in the UV and visible regions at 290, 315 and 480 nm.