Publications by authors named "Awasthi K"

Modulation in cellular function and cell death through electrostimulation of intracellular organelles with the application of 50 ns pulsed electric field (nsPEF) have been investigated in breast cancerous MCF7 and normal MCF10A cells by developing a three-dimensional microelectrode device integrated with a fluorescence microscope. The findings revealed that nsPEF induced distinct effects on intracellular functions and dynamics in MCF7 and MCF10A cells. MCF10A cells exhibited significantly higher survivability than MCF7 cells, with different modes of cell death observed between them.

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The development of supercapacitors is pivotal for sustainable energy storage solutions, necessitating the advancement of innovative electrode materials to supplant fossil-fuel-based energy sources. Zinc oxide (ZnO) is widely studied for use in supercapacitor electrodes because of its beneficial physicochemical properties, including excellent chemical and thermal stability, semiconducting characteristics, low cost, and environmentally friendly nature. In this study, ZnO nanorods were synthesized using a simple hydrothermal method and then combined with various Ni-based layered double hydroxides (LDHs) [NiM'-LDHs (M' = Mn, Co, and Fe)] to improve the electrochemical performance of the ZnO nanorods.

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Aqueous zinc ion hybrid supercapacitors (ZIHSCs) are promising as low-cost and safe energy storage devices for next-generation applications. Still, their energy-power performance and durability are far from satisfactory. Here, we present an energy-dense, and ultrastable ZIHSC realized using activated porous carbons derived from chilli-stems.

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To address the escalating demand for efficient CO separation technologies, we introduce novel membranes utilizing natural polymer guar gum (GG), conjugate polymer (poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)) PEDOT:PSS, and bimetallic PdPt nanoparticles. Bimetallic PdPt nanoparticles were synthesized using the wet chemical method and characterized using X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) techniques. The morphologies, chemical bonds, functional groups, and mechanical properties of the fabricated membranes were characterized using various techniques.

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This new collection in , , and will focus on the design of multifunctional hybrid nanomaterials for different applications and on interfacing nanomaterials with biological systems for translational studies.

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Hydrogen separation has significant importance in diverse applications ranging from clean energy production to gas purification. Membrane technology stands out as a low-cost and efficient method to address the purpose. The development of efficient gas-sensitive materials can further bolster the membrane's performance.

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Although many dyes have been introduced into cellulose, whether bound to its backbone or within a cellulose matrix, few studies have determined whether the backbone statically or dynamically quenches the photoluminescence of the dye. To advance cellulosic fluorescent films, the influence of the cellulose backbone on photoluminescence must be understood. We determined the fluorescence properties of fluorescein isothiocyanate (FITC) and fluorescein-labeled cellulose (FLC) in water and alcohol, including their quantum yields [Formula: see text], lifetimes [Formula: see text], and rates of radiative [Formula: see text] and nonradiative [Formula: see text] decay.

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Article Synopsis
  • This paper explores using acoustic waves in piezoelectric plates to detect the five basic tastes: salt, sweet, sour, umami, and bitter, through experiments with specific aqueous solutions.
  • Different liquids were analyzed based on their physical properties, and changes in acoustic wave propagation were measured to differentiate between tastes.
  • The study suggests that the developed acoustic electronic tongue can create unique response patterns for various liquids, paving the way for efficient analysis of food and other substances without extensive chemical testing.
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This study presents a novel, environmentally sustainable method for the synthesis of graphene oxide (GO) sheets decorated uniformly with silver nanoparticles (Ag NPs) ranging in size from 4 to 34 nm. The reduction of AgNO is achieved using an extract derived from Cucumis callosus fruit, which serves as a dual-function stabilizing and reducing agent. Cucumis callosus, belonging to the Cucurbitaceae family and native to regions such as India, South America, Thailand, Africa, and Egypt, is recognized for its substantial nutritional and medicinal value, encompassing antioxidant, antidiabetic, anticancer, and anti-inflammatory properties.

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This work is primarily focused on overcoming the limitations of polymeric membranes in achieving the balance between permeability and selectivity of the separation performance. The filler, Zeolitic imidazole framework -67 (ZIF-67) nanoparticles were synthesised in cubical morphology using hexadecyltrimethylammonium bromide (CTAB) as a surfactant via the wet-chemical method. The uniform particles with particle sizes ranging between 120-180 nm were incorporated into the polyvinylidene fluoride (PVDF) matrix to fabricate mixed matrix membranes via the phase inversion method.

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-Nitrophenol (-NP) is known as a common contaminant found in wastewater, agricultural runoff, and industrial effluents which can degrade water quality and cause potential carcinogenic and toxic effects on the human body. Its detection is essential for public health, industrial safety, environmental protection, and regulatory compliance, underscoring its broad applicability. In this study, a novel electrochemical sensor based on polypyrrole (PPy) flowers assembled nanotubes was developed for the sensitive determination of -NP.

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Coronavirus disease 2019 (COVID-19) is a disease that caused a global pandemic and is caused by infection of severe acute respiratory syndrome coronavirus 2 virus. It has affected over 768 million people worldwide, resulting in approximately 6900000 deaths. High-risk groups, identified by the Centers for Disease Control and Prevention, include individuals with conditions like type 2 diabetes mellitus (T2DM), obesity, chronic lung disease, serious heart conditions, and chronic kidney disease.

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Herein, we have isolated onion-like nanocarbon (ONC) from the exhaust soot of diesel engines and further doped it with nitrogen (N) and sulfur (S) to fabricate N,S-co-doped ONC (N-S-ONC). To explore its application feasibility, we have assembled an aqueous Zn-ion hybrid supercapacitor (ZIHSC) with a N-S-ONC cathode, which attains high specific capacitance with good rate capability. In-depth analyses suggest that the mechanism of charge storage in the ONC is governed by both capacitive-controlled and diffusion-controlled processes, with the capacitive processes leading at all sweep rates.

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One of the frontier research areas in the field of gas sensing is high-performance room temperature-based novel sensing materials, and new family of low-cost and eco-friendly carbon nanomaterials with a unique structure has attracted significant attention. In this work, we propose a novel low-cost flexible room temperature ammonia gas sensor based on nitrogen-doped carbon nano-onions/polypyrrole (NCNO-PPy) composite material mounted low-cost membrane substrate was synthesized by combining hydrothermal and in-situ chemical polymerization methods. The proposed flexible sensor revealed high sensing performance when employed as the sensing material for ammonia detection at room temperature.

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Introduction: Globally malaria programmes have adopted approaches to community engagement (ACE) to design and deliver malaria interventions. This scoping review aimed to understand, map, and synthesise intervention activities guided by ACE and implemented by countries worldwide for the prevention, control and elimination of malaria.

Methods: Three databases (Web of Science, Proquest, and Medline) were searched for peer-reviewed, primary studies, published in English between 1 January 2000 and 31 December 2022.

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Borophene, a 2D material exhibiting unique crystallographic phases like the anisotropic atomic lattices of β and X phases, has attracted considerable attention due to its intriguing Dirac nature and metallic attributes. Despite surpassing graphene in electronic mobility, borophene's potential in energy storage and catalysis remains untapped due to its inherent electrochemical and catalytic limitations. Elemental doping emerges as a promising strategy to introduce charge carriers, enabling localized electrochemical and catalytic functionalities.

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In the dynamic landscape of industrial processes, membrane technology offers a paradigm shift beyond energy-intensive separation techniques, exemplifying a progressive leap toward sustainability. In this regard, highly flexible and uniform poly(3,4-ethylenedioxythiophene)polystyrenesulfonate (PEDOT:PSS)-engineered membranes at a reduced thickness have been fabricated on track-etched poly(ethylene terephthalate) (PET) substrates. The membranes were functionalized and embedded with platinum nanoparticles (Pt NPs) having a higher affinity toward H gas.

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Through this work, we are reporting high-performance ZIF-8 @polycarbonate nanocomposite membranes with satisfactory structural stability for improving the gas separation performance. ZIF-8 nanoparticles were synthesised using the wet chemical route with cubic morphology and controlled size using CTAB as a surfactant. The membranes were prepared using the solution casting method by adding ZIF-8 filler at various concentrations.

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Zinc ion hybrid supercapacitors (ZIHSCs) are truly promising as next-generation high-performance energy storage systems because they could offer high energy density like batteries while exhibiting high power output and long cycle life traits of supercapacitors. The key point of constructing a high-performance ZIHSC is to couple the Zn anode with an appropriate cathode material, which has high theoretical capacity, cost-effectiveness, and intrinsic safety features. In this work, we have demonstrated the potentiality of S, N co-doped porous carbon nanocubes (S, N-CNCs) as a cathode material for devising a ZIHSC with excellent energy density and cycle life.

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Zinc-ion batteries (ZIBs) have attracted tremendous interest from the scientific community in recent years due to their extreme safety, cost-effectiveness, environmental benignity and the unique properties of the Zn anode. However, more suitable cathode materials are needed to achieve their potential widespread applications. MoS, a 2D layered material with fascinating properties, could also serve as a cathode in ZIBs but is rarely studied due to its limited interlayer spacing, poor ionic/electronic conductivity and hydrophobicity.

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Long non-coding-RNAs (lncRNAs) are an expanding set of cis-/trans-regulatory RNA genes that outnumber the protein-coding genes. Although being increasingly discovered, the functional role of the majority of lncRNAs in diverse biological conditions is undefined. Increasing evidence supports the critical role of lncRNAs in the emergence, regulation, and progression of various viral infections including influenza, hepatitis, coronavirus, and human immunodeficiency virus.

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Herein, we are reporting the carbon nano onions (CNO)-based sulphonated poly(ethersulfone) (SPES) composite membranes by varying CNO content in SPES matrix for water desalination applications. CNOs were cost-effectively synthesized using flaxseed oil as a carbon source in an energy efficient flame pyrolysis process. The physico- and electrochemical properties of nanocomposite membranes were evaluated and compared to pristine SPES.

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Biofilms are made up of bacterial colonies and their extracellular polymeric substances (EPS) matrix, which protects the bacteria from adverse environmental conditions. The increasing drug resistivity of pathogenic bacteria is becoming an emergency for developing new antibacterial agents. In this study, we have synthesized the zinc oxide nanoparticles (ZnO NPs) using the leaf extract of Saraca asoca plant, and the antibacterial and antibiofilm activity of green synthesized ZnO NPs was measured against the biofilm-producing bacteria Bacillus subtilis.

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Microplastic, which is of size less than 5 mm, is gaining a lot of attention as it has become a new arising contaminant because of its ecophysiology impact on the aquatic environment. These microplastics are found in freshwater or drinking water and are the major carriers of pollutants. Removal of this microplastic can be done through the primary treatment process, secondary treatment process, and tertiary treatment process.

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