Entropy of Branching Out: Linear versus Branched Alkylthiols Ligands on CdSe Nanocrystals.

Surface ligands of semiconductor nanocrystals (NCs) play key roles in determining their colloidal stability and physicochemical properties and are thus enablers also for the NCs flexible manipulation toward numerous applications. Attention is usually paid to the ligand binding group, while the impact of the ligand chain backbone structure is less discussed. Using isothermal titration calorimetry (ITC), we studied the effect of structural changes in the ligand chain on the thermodynamics of the exchange reaction for oleate coated CdSe NCs, comparing linear and branched alkylthiols.

T cell receptor beta germline variability is revealed by inference from repertoire data.

Background: T and B cell receptor (TCR, BCR) repertoires constitute the foundation of adaptive immunity. Adaptive immune receptor repertoire sequencing (AIRR-seq) is a common approach to study immune system dynamics. Understanding the genetic factors influencing the composition and dynamics of these repertoires is of major scientific and clinical importance.

A Tale of Tails: Thermodynamics of CdSe Nanocrystal Surface Ligand Exchange.

The surface ligands of semiconductor nanocrystals (NCs) are central for determining their properties and for their flexible implementation in diverse applications. Thus far, the thermodynamic characteristics of ligand exchange reactions were attained by indirect methods. Isothermal titration calorimetry is utilized to directly and independently measure both the equilibrium constant and the reaction enthalpy of a model ligand exchange reaction from oleate-capped CdSe NCs to a series of alkylthiols.