The Increasing Surface Ozone and Tropospheric Ozone in Antarctica and Their Possible Drivers.

A comprehensive analysis of the temporal evolution of tropospheric ozone in Antarctica using more than 25 years of surface ozone and ozonesonde measurements reveals significant changes in tropospheric ozone there. It shows a positive trend in ozone at the surface and lower and mid-troposphere, but a negative trend in the upper troposphere. We also find significant links between different climate modes and tropospheric ozone in Antarctica and observe that changes in residual overturning circulation, the strength of the polar vortex, and stratosphere-troposphere exchange make noticeable variability in tropospheric ozone.

ENSO and Southeast Asian biomass burning modulate subtropical trans-Pacific ozone transport.

Trans-Pacific transport of enhanced ozone plumes has been mainly attributed to fossil fuel combustion in Asia in spring, but less attention has been paid to vegetation fires in Asia. Here we show that the El Niño-Southern Oscillation (ENSO)-modulated fires in Southeast Asia, rather than Asian fossil fuel plumes, dominate the interannual variability of springtime trans-Pacific transport of ozone across the entire North Pacific Ocean. During El Niño springs, the intensified fires from both the Indochinese Peninsula and Indonesia, together with large-scale circulation anomalies, result in enhanced ozone plumes that stretch over 15 000 km in both the lower-middle and upper troposphere.

Surface and tropospheric ozone trends in the Southern Hemisphere since 1990: possible linkages to poleward expansion of the Hadley circulation.

Increases in free tropospheric ozone over the past two decades are mainly in the Northern Hemisphere that have been widely documented, while ozone trends in the Southern Hemisphere (SH) remain largely unexplained. Here we first show that in-situ and satellite observations document increases of tropospheric ozone in the SH over 1990-2015. We then use a global chemical transport model to diagnose drivers of these trends.