Organic aerosols (OA) are a significant component of fine particulate matter in the ambient air and are formed through primary and secondary processes. Primary organic aerosols (POA) are directly released from sources, while secondary organic aerosols (SOA) are formed through the oligomerization and/or oxidation of volatile organic compounds (VOCs) in the atmosphere. Recently, there has an increasing attention on the SOA budgets, their formation pathways, and photochemical evolution due to their impacts on climate and human health.
View Article and Find Full Text PDFIndo-Gangetic Plain (IGP) experiences a heavy load of particulate pollution impacting the 9 % of the global population living in this region. The present study examines the dithiothreitol (DTT) assay-based oxidative potential (OP) of PM and the major sources responsible for the observed OP over the central IGP (Kanpur) during winter. The volume normalized OP (OP) of PM varied from 2.
View Article and Find Full Text PDFWe investigated the influence of biomass burning (BURN), Diwali fireworks, and fog events on the ambient fine particulate matter (PM) oxidative potential (OP) during the postmonsoon (PMON) and winter season in Delhi, India. The real-time hourly averaged OP (based on a dithiothreitol assay) and PM chemical composition were measured intermittently from October 2019 to January 2020. The peak extrinsic OP (OP: normalized by the volume of air) was observed during the winter fog (WFOG) (5.
View Article and Find Full Text PDFIt is well established that light-absorbing organic aerosols (commonly known as brown carbon, BrC) impact climate. However, uncertainties remain as their contributions to absorption at different wavelengths are often ignored in climate models. Further, BrC exhibits differences in absorption at different wavelengths due to the variable composition including varying sources and meteorological conditions.
View Article and Find Full Text PDFDelhi, the capital of India, suffers from heavy local emissions as well as regional transport of air pollutants, resulting in severe aerosol loadings. To determine the sources of these pollutants, we have quantified the mass concentrations of 26 elements in airborne particles, measured by an online X-ray fluorescence spectrometer with time resolution between 30 min and 1 h. Measurements of PM and PM (particulate matter <10 μm and < 2.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2020
Light-absorbing organic aerosol (brown carbon (BrC)) can significantly affect Earth's radiation budget and hydrological cycle. Biomass burning (BB) is among the major sources of atmospheric BrC. In this study, day/night pair (10-h integrated) of ambient PM were sampled every day before (defined as T1, n = 21), during (T2, n = 36), and after (T3, n = 8) a large-scale paddy-residue burning during October-November over Patiala (30.
View Article and Find Full Text PDFA simple, rapid, accurate and precise RP-HPLC method was developed for the determination of stigmasterol in botanical extract of . Separation was achieved with acetonitrile and acetic acid in water (75:25% v/v) in isocratic mode at 210 nm. Single sharp peak of standard stigmasterol was detected at retention time 3.
View Article and Find Full Text PDFCompost salinity is an ongoing concern for compost producers, especially with certain feedstocks and in arid or semiarid regions. Current testing protocols call for sampling and testing ex-situ via 1:5 (w/v) slurries via electrical conductance. For this research an alternate approach has been proposed, the use of portable X-ray fluorescence (PXRF) spectrometry.
View Article and Find Full Text PDFSize-segregated particulate pollutants (PM, PM, PM, PM and PM) were collected over Patiala (30.33°N, 76.40°E; 250 m amsl), a semi-urban city located in northwestern Indo-Gangetic Plain (IGP), during October, 2012 to September, 2013.
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