Publications by authors named "Assem T Mohamed"

Assigned to their outstanding physicochemical properties, TiO-based materials have been studied in various applications. Herein, TiO doped with different Mo contents (Mo-TiO) was synthesized via a microwave-assisted solvothermal approach. This was achieved using titanium (IV) butoxide and molybdenum (III) chloride as a precursor and dodecylamine as a surface directing agent.

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The production of syngas dry reforming of methane (DRM) has drawn tremendous research interest, ascribed to its remarkable economic and environmental impacts. Herein, we report the synthesis of K, Na, Cs, Li, and Mg-promoted Ni/LaO using solution combustion synthesis (SCS). The properties of the catalysts were determined by N physisorption experiments, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectrometry (XPS), and H-TPR (temperature programmed reduction).

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The catalytic combustion of methane (CCM) has been extensively studied owing to the wide use of methane in motor vehicles and power generation turbines. However, the absence of polarizability and the high C-H bond strength are considered to be the main drawbacks that limit its oxidation by traditional catalytic converters. Palladium-based catalysts are recognized as the benchmark catalysts for methane oxidation, especially under oxidizing conditions, and their activity is dependent on different parameters such as size, dispersion, and the nature of the support.

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In the last few decades, TiO has been widely used in different types of photocatalytic applications. However, the relatively large optical band gap (∼3.2 eV), low charge carrier mobility and consequently its low quantum efficiency limit its photocatalytic activity.

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Copper oxide (CuO) nanoparticles have received considerable interest as active and inexpensive catalysts for various gas-solid reactions. The CuO reducibility and surface reactivity are of crucial importance for the high catalytic activity. Herein, we demonstrate that the reducibility and stability of CuO nanoparticles can be controlled and tailored for the high catalytic activity of CO oxidation.

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