Complex network-based multistep forecasting model for hyperchaotic time series.

We present a method for predicting hyperchaotic time series using a complex network-based forecasting model. We first construct a network from a given time series, which serves as a coarse-grained representation of the underlying attractor. This network facilitates multistep forecasting by capturing the local nonlinearity of the dynamics and offers superior accuracy over more extended periods than traditional methods.

Mitral Annular Disjunction in Heritable Thoracic Aortic Disease: Insights From the Montalcino Aortic Consortium.

Background: Mitral annular disjunction (MAD), posterior displacement of the mitral valve leaflet hinge point, predisposes to arrhythmias or sudden cardiac death. We evaluated the burden of MAD, mitral valve prolapse (MVP), and mitral regurgitation (MR) by heritable thoracic aortic disease gene in a cross-sectional analysis of 2014-2023 data in the Montalcino Aortic Consortium registry.

Methods And Results: MAD was determined by direct measurement of echocardiographic images.

A scalable approach using a gCN-covalent organic framework hybrid catalyst towards sustainable hydrogen production from seawater and wastewater.

The photocatalytic generation of H using covalent organic frameworks (COFs) is gaining more interest. While numerous reports have focused on the production of H from deionized water using COFs, the inability to produce H from industrial wastewater or seawater is a common limitation in many reported catalysts. Additionally, many of these reports lack a clear path to scale up the catalyst synthesis.

Minor limonoid constituents from by simultaneous isolation using supercritical fluid chromatography and their biological activities.

This study reports simultaneous isolation of three new limonoids (1-3), six known regio isomers (6, 7, 9-12), and three more known limonoids (4, 5, 8) from () seeds. Structures of these compounds were determined extensive study of their 1D/2D-NMR and mass spectral data. Known limonoids (4-12) were identified by comparing their physical and spectroscopic data with literature values.

Correction: Efficient amidation of weak amines: synthesis, chiral separation by SFC, and antimicrobial activity of -(9,10-dioxo-9,10-dihydroanthracen-1-yl)carboxamide.

Correction for 'Efficient amidation of weak amines: synthesis, chiral separation by SFC, and antimicrobial activity of -(9,10-dioxo-9,10-dihydroanthracen-1-yl) carboxamide' by Kathiravan Asokan , , 2024, , 309-319, https://doi.org/10.1039/D3OB01774E.

Children's vulnerabilities and pathways to conflict with the law: Insights from Swatantra Clinic, a specialised mental health service at a tertiary care centre in India.

'Swatantra-Clinic' at NIMHANS, India, provides mental healthcare to vulnerable children. This study describes the clinical profile, vulnerability and protective factors of 77 adolescents in conflict with the law (CICL). 90.

Efficient amidation of weak amines: synthesis, chiral separation by SFC, and antimicrobial activity of -(9,10-dioxo-9,10-dihydroanthracen-1-yl) carboxamide.

An effective and straightforward method for the synthesis of 1-aminoanthracene-9,10-dione carboxamides by coupling a weakly reactive amine, 1-aminoanthracene-9,10-dione, and sterically hindered carboxylic acids was achieved using COMU as the coupling agent. Furthermore, making use of the advantages associated with the super-critical fluid chromatography (SFC) technique, a simplified and straightforward method for the chiral separation of optically active amide derivatives from the impurities associated with the reaction mixture, in a single step, was demonstrated. The antimicrobial activity of selected 1-aminoanthracene-9,10-dione carboxamides was studied.

Tuning the physiochemical properties of polycaprolactone-hydroxyapatite composite films by gamma irradiation for biomedical applications.

Physiochemical properties of polycaprolactone-hydroxyapatite (PCL-HAp) composites were investigated in the pristine and after irradiation of γ rays (25, 50, 75, and 100 kGy). PCL-HAp composites were synthesized by solvent evaporation and characterized using spectroscopic methods as well as biological assays. The surface roughness (RMS) of the irradiated composite film (at 75 kGy) was 80 times higher than that of the pristine.

Intriguing physicochemical properties and impact of co-dopants on N-doped graphene oxide based ZnS nanowires for photocatalytic application.

Superparamagnetic N-doped graphene oxide (GO)- with ZnS nanowires was synthesized by a one-step hydrothermal method by doping dilute amounts of Ga, Cr, In, and Al ions for water treatment and biomedical applications. In these experiments, to enhance their properties, 2% of Ga, In, and or Al were codoped along with 2% Cr ions in these ZnS nanowires. The nanocomposite with the composition, InCrZnS, has better photocatalytic efficiency than other co-doped nanocomposites.

Outcomes of Keller Gap Arthroplasty for Plantar Hallux Interphalangeal Joint Ulcers in Patients With Diabetes Mellitus.

Background: Hallux ulcers are known for their recurrence and associated risk for future amputations. Traditional nonsurgical external offloading methods have poor compliance rates, and the data is sparse on surgical offloading of hallux ulcers. We performed this study to analyze the outcomes of Keller excision gap arthroplasty of the first metatarsophalangeal joint in patients with a neuropathic plantar hallux interphalangeal joint (IPJ) ulcer in patients with diabetes mellitus.

Fuel use in small-scale fishing vessels along the southeast coast of India: a comparative study to ascertain possible reasons and potential recommendations for effective management.

Regulating the fuel consumption of small-scale fishing vessels could help to keep global warming well below 1.5 °C and lead to effective management in small-scale fisheries (SSF) of developing countries like India. In this regard, a bottom-up approach was carried out to collect the requisite data to explore the fuel consumption of small-scale fishing vessels along India's southeast coast.

Parachute Method: A Novel Method to Retrieve a Stuck Degloved Finger.

An entrapped finger is a relatively uncommon domestic injury. When the finger gets stuck proximal to the proximal interphalangeal joint, the resultant distal edema and inappropriate attempts at retrieval can result in circumferential degloving of the skin and injury to the neurovascular structures. We report a technique that can be used in such circumstances.

Oligothiophene-Ring-Strapped Perylene Bisimides: Functionalizable Coaxial Donor-Acceptor Macrocycles.

Aesthetic designs from nature enable new knowledge to be gained and, at the same time, inspire scientific models. In this context, multicomponent macrocycles embody the advantage of precisely positioning the structural units to achieve efficient communication between them. However, the construction of a functionalizable macrocycle for ultrafast charge separation and stabilization has not been attempted.

Spin and valence variation in cobalt doped barium strontium titanate ceramics.

In the present decade, owing to half-metallic ferromagnetism, controlled 3d transition metal-doping based defect engineering in oxide perovskites attracts considerable attention in the pursuit of spintronics. We aim to investigate the electronic structure of Co-doped barium strontium titanate (BaSrCoTiO where = 0, 0.1, 0.

Evaluation and Correlation of Condylar Cortication by Cone-Beam Computed Tomography: A Retrospective Study.

Background: Temporomandibular joint (TMJ) is a ginglymo-diarthroidial joint with fibroelastic cartilage. The chondrogenesis initiates from the 12 week of intrauterine life and the development of condyle is associated with growth. The condylar cortication shows distinct morphological variation for each individual in each stage of their life.

Supramolecular Self-Assembly Mediated by Multiple Hydrogen Bonds and the Importance of C-S···N Chalcogen Bonds in '-(Adamantan-2-ylidene)hydrazide Derivatives.

The present article comprehensively examines six '-(adamantan-2-ylidene)hydrazide derivatives using the Hirshfeld surface analysis, PIXEL energy for molecular dimers, lattice energies for crystal packing, and topological analysis for intramolecular and intermolecular interactions. The crystal structure of one of the '-(adamantan-2-ylidene)hydrazide derivatives, namely, '-(adamantan-2-ylidene)-5-bromothiophene-2-carbohydrazide , CHNOSBr, has been determined and analyzed in detail along with five closely related structures. The molecular conformation of is locked by an intramolecular C-S···N chalcogen bond as found in one of its closely related structure, namely, '-(adamantan-2-ylidene)thiophene-2-carbohydrazide.

Donor-acceptor based solvent-free organic liquid hybrids with exciplex emission and room temperature phosphorescence.

Solvent-free organic liquids are well-known for their excellent luminescence features. Hence, the recent developments in this area have marked them as potential emitters with high quantum yield and enhanced processability. The support of an available liquid matrix enables doping to deliver hybrid liquids with intriguing luminescence features.

Testing for nonlinearity in nonstationary time series: A network-based surrogate data test.

The classical surrogate data tests, which are used to differentiate linear noise processes from nonlinear processes, are not suitable for nonstationary time series. In this paper, we propose a surrogate data test that can be applied on both stationary time series as well as nonstationary time series with short-term fluctuations. The method is based on the idea of constructing a network from the time series, employing a generalized symbolic dynamics method introduced in this work, and using any one of the several easily computable network parameters as discriminating statistics.

Role of Interfacial Defects in Photoelectrochemical Properties of BiVO Coated on ZnO Nanodendrites: X-ray Spectroscopic and Microscopic Investigation.

Synchrotron-based X-ray spectroscopic and microscopic techniques are used to identify the origin of enhancement of the photoelectrochemical (PEC) properties of BiVO (BVO) that is coated on ZnO nanodendrites (hereafter referred to as BVO/ZnO). The atomic and electronic structures of core-shell BVO/ZnO nanodendrites have been well-characterized, and the heterojunction has been determined to favor the migration of charge carriers under the PEC condition. The variation of charge density between ZnO and BVO in core-shell BVO/ZnO nanodendrites with many unpaired O 2p-derived states at the interface forms interfacial oxygen defects and yields a band gap of approximately 2.

Hybrid genome assembly of reveals the novel finding of chromosomal integration of an IncFII plasmid carrying a gene.

Azithromycin is increasingly being used for the treatment of shigellosis despite a lack of interpretative guidelines and with limited clinical evidence. The present study determined azithromycin susceptibility and correlated this with macrolide-resistance genes in spp. isolated from stool specimens in Vellore, India.

Thermoelectric properties of GaN with carrier concentration modulation: an experimental and theoretical investigation.

The present work investigates the less explored thermoelectric properties of the n-type GaN semiconductor by combining both experimental and computational tools. The Seebeck coefficients of GaN epitaxial thin films were experimentally measured in the wide temperature range from 77 K to 650 K in steps of ∼10 K covering both low and high-temperature regimes as a function of the carrier concentration (2 × 1016, 2 × 1017, 4 × 1017 and 8 × 1017 cm-3). The measured Seebeck coefficient at room temperature was found to be highest (-374 μV K-1) at the lowest concentration of 4 × 1016 cm-3, and decreases in magnitude monotonically (-327.