Hydration behavior of asparagine: an approach using time domain reflectometry at low temperatures.

The dielectric behavior of Asparagine (CHNO) in water over the frequency range of 10 MHz to 30 GHz in the temperature region of 278.15-303.15 K in a step of 5 K has been carried out using time domain reflectometry (TDR) at various concentrations of asparagine.

Temperature-dependent hydration behavior of aqueous lysine: an approach towards protein binding through dielectric spectroscopy.

Present work reports interaction between water and amino acid lysine for understanding the physicochemical properties that will be useful in the structure formation of protein. The dielectric relaxation of aqueous lysine was systematically investigated over a temperature range spanning from 298.15 K to 278.

Water dynamics on the structural properties of some NSAID's with leucine in the picosecond region using time domain spectroscopy.

Concentration-dependent dielectric response for non-steroidal anti-inflammatory drugs (NSAIDs): Aceclofenac (ACF) and Diclofenac (DCF) in the aqueous leucine solution have been reported at different concentrations and temperatures (298.15 K to 283.15 K).

Temperature-dependent dielectric relaxation and hydrophobicity of aqueous alanine using time domain reflectometry.

Physical, chemical and microbiological stability of the materials is affected by the rotational and translational mobility of free and hydrated water. The role of water in areas such as protein hydration and enzyme activity, food technology, lyophilization and polymers hydration is, therefore, important and can be well understood in terms of dielectric relaxation spectroscopy. Concentration and temperature-dependent hydrophobicity of amino acid is reflected in their tendencies to appear in appropriate positions in proteins.

Dielectric Relaxation and Hydration Interactions for Protic and Aprotic Ionic Liquids using Time Domain Reflectometry.

H-Bonding abilities of ionic liquids (ILs) along with hydrophobicity and cooperativity effects increases their hydration numbers making them capable for dissolving sparingly soluble organic molecules in aqueous or polar nonaqueous media, and hence ILs are potential candidates in pharmaceutical and medicinal sciences besides the different technological and academic interests. In this work, dielectric spectra were measured and analyzed for diethylammonium-based protic ionic liquids (PILs), imidazolium-based aprotic ionic liquids (APILs), and their aqueous solutions (∼0.02 to ∼0.

Relaxation dynamics and thermophysical properties of vegetable oils using time-domain reflectometry.

Dielectric relaxation studies of vegetable oils are important for insights into their hydrogen bonding and intermolecular dynamics. The dielectric relaxation and thermo physical properties of triglycerides present in some vegetable oils have been measured over the frequency range of 10 MHz to 7 GHz in the temperature region 25 to 10 °C using a time-domain reflectometry approach. The frequency and temperature dependence of dielectric constants and dielectric loss factors were determined for coconut, peanut, soya bean, sunflower, palm, and olive oils.

Structural behavior of alcohol-1,4-dioxane mixtures through dielectric properties using TDR.

The values of complex permittivity for alcohol-1,4-dioxane (DX) mixtures with various concentrations have been determined in the frequency range 10 MHz to 20 GHz using the time domain reflectometry (TDR) method. Numbers of hydrogen bonds between alcohol-alcohol and alcohol-dioxane pairs are estimated from the values of the static dielectric constant by using the Luzar model. The model provides a satisfactory explanation of the experimental results related to the static dielectric constant.

Dielectric properties of ethyleneglycol-1,4-dioxane mixtures using TDR method.

Complex permittivity has been determined for mixtures of ethyleneglycol-1,4-dioxane (EG-DX) with various concentrations in the frequency range from 100 MHz to 30 GHz at 25 degrees C by time domain reflectometry (TDR). A primary process with an asymmetric shape and a Debye-type small-amplitude high-frequency process are observed for each mixture. The deviation of the relaxation time for the primary process from that of the ideal mixture shows a maximum value at a mole fraction of 1,4-dioxane, xDX approximately =0.