Publications by authors named "Ashish A Vaidya"

Article Synopsis
  • Biomimetic materials benefit from adding specific chemical features to their surfaces, but preserving their roughness while doing so is a challenge.
  • Researchers developed a method using a water-based layer-by-layer approach to modify these materials effectively while maintaining surface texture.
  • The resulting PDMS-replica with fluorinated groups displayed superhydrophobic and oil-repellent properties, making it suitable for various applications in different environments.
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The oil-repellent performance of a poly(dimethylsiloxane)-based biomimetic replica (PDMS-replica) was tuned by modifying its surface chemical composition. PDMS-replica possessing a complementary combination of hierarchical roughness and mixed -CF(3) and -SiCH(3) terminal functionality was prepared in the presence of a surface-modifying agent, using nanocasting based on soft lithography. PDMS-replica showed superhydrophobicity and enhanced oil repellency, theta(oil) approximately 86 degrees .

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This paper describes the preparation and surface characterization of maleimide-activated silicone elastomer (PDMS(MCC)) followed by covalent functionalization using thiol-terminated DNA sequences (primary oligo). The stability of this attachment chemistry was demonstrated by the retention of the primary oligo through the process of hybridization with a labeled complementary DNA sequence. In these studies, the hybridized labeled DNA oligomers were detected using confocal fluorescence microscopy.

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