The discharge of toxic dye effluents from industry is a major concern for environmental pollution and toxicity. These toxic dyes can be efficiently removed from waste streams using a photocatalysis process involving visible light. Due to its simple synthesis procedure, inexpensive precursor, and robust stability, graphitic carbon nitride (g-CN, or CN) has been used as a visible light responsive catalyst for the degradation of dyes with mediocre performance because it is limited by its low visible light harvesting capability due to its wide bandgap and fast carrier recombination rate.
View Article and Find Full Text PDFCopper tin sulfide, CuSnS (CTS), a ternary transition-metal chalcogenide with unique properties, including superior electrical conductivity, distinct crystal structure, and high theoretical capacity, is a potential candidate for supercapacitor (SC) electrode materials. However, there are few studies reporting the application of CuSnS or its composites as electrode materials for SCs. The reported performance of the CuSnS electrode is insufficient regarding cycle stability, rate capability, and specific capacity; probably resulting from poor electrical conductivity, restacking, and agglomeration of the active material during continued charge-discharge cycles.
View Article and Find Full Text PDFCarbon quantum dots (CQD) as the result of their exceptional physical and chemical properties show tremendous potential in various field of applications like cell imaging and doping of CQDs with elements like nitrogen and phosphorous increase its fluorescence property. Herein, we have synthesized fluorescent nitrogen and phosphorous codoped carbon quantum dots (NPCQDs) via a one-pot hydrothermal method. Sesame oil, L-Aspartic acid, and phosphoric acid were used as carbon, nitrogen, and phosphorous sources, respectively.
View Article and Find Full Text PDFThis work describes photocatalytic application of γ-alumina (γ-AlO) surface-anchored palladium and palladium oxide nanoparticles (Pd-γ-AlO and PdO-γ-AlO NPs) synthesized by a novel co-precipitation technique. The palladium(0) NPs (Pd-γ-AlO) were formed by calcination of the sample in inert medium, whereas PdO NPs (PdO-γ-AlO) were obtained by calcination of the sample in atmospheric oxygen. As-synthesized Pd-γ-AlO and PdO-γ-AlO NPs are characterized by X-ray diffraction, Fourier transform-infrared spectroscopy, field emission scanning electron microscopy and photoluminescence (PL) spectra.
View Article and Find Full Text PDFMetal oxide nanomaterials are one of the preferences as antibacterial active materials. Due to its distinctive electronic configuration and suitable properties, ZnO is one of the novel antibacterial active materials. Nowadays, researchers are making a serious effort to improve the antibacterial activities of ZnO by forming a composite with the same/different bandgap semiconductor materials and doping of ions.
View Article and Find Full Text PDFThis work reports the synthesis and application of magnetic rGO/FeO NCs using a pod extract of L. as areducing agent. GO was synthesized by a modified Hummers method, however GO was reduced using the plant extract to produce rGO.
View Article and Find Full Text PDFIn this study, we report a green and economical hydrothermal synthesis of fluorescent-nitrogen-doped carbon quantum dots (NCQDs) using citrus lemon as a carbon source. The prepared NCQDs possess high water solubility, high ionic stability, resistance to photobleaching, and bright blue color under ultraviolet radiation with a high quantum yield (∼31%). High-resolution transmission electron microscopy (HRTEM) results show that the prepared NCQDs have a narrow size distribution (1-6 nm) with an average particle size of 3 nm.
View Article and Find Full Text PDFWe report a facile one-pot green synthesis of zinc oxide (ZnO) nanostructures using aqueous leaf extract of L. as the reducing and capping agent. The optical properties, structure and morphology of the as-synthesized ZnO nanostructures have been characterized by UV-Visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) supported with energy dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM).
View Article and Find Full Text PDFAs a remedy for environmental pollution, a simple synthesis approach has been developed to prepare nitrogen doped carbon quantum dot/magnetite nanocomposites (FeO@NCQDs NCs) using non-toxic and cost effective lemon juice as precursor for removal of organic dye pollutant. FeO@NCQDs NCs were characterized by using UV-Vis spectroscopy, FTIR, XRD, FESEM, EDS, TEM, VSM and TGA/DTA. TEM results show spherical shaped FeO@NCQDs NCs with an average particle size of 5 nm.
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