Environmental radiological baseline in unconventional oil and gas areas of Mexico.

Environmental radioactivity study was performed in unconventional hydrocarbons areas for the first time in Mexico, where four unconventional hydrocarbon exploratory wells (UHEW) are planned. This study assesses natural radiological conditions in areas around UHEW. Equivalent dose rate distribution displayed in Geographic Information System (GIS) had a maximum of 1.

Deep-Eutectic Solvents as MWCNT Delivery Vehicles in the Synthesis of Functional Poly(HIPE) Nanocomposites for Applications as Selective Sorbents.

We report an alternative green strategy based on deep-eutectic solvents (DES) to deliver multiwalled carbon nanotubes (MWCNTs) for a bottom-up approach that allows for the selective interfacial functionalization of nonaqueous poly(high internal phase emulsions), poly(HIPEs). The formation and polymerization of methacrylic and styrenic HIPEs were possible through stabilization with nitrogen doped carbon nanotube (CN) and surfactant mixtures using a urea-choline chloride DES as a delivering phase. Subtle changes in CN concentration (less than 0.

Europium-doped aluminum oxide phosphors as indicators for frontal polymerization dynamics.

In this study, we present an inexpensive and practical method that allows the monitoring and visualization of front polymerization, propagation, and dynamics. Commercially available europium-doped aluminum oxide powders were combined with video imaging to visualize free-radical propagating polymer fronts. In order to demonstrate the applicability of this method, frontal copolymerization reactions of propoxylated glycerin triacrylate (EB53), pentaerythritol triacrylate (PETA), and pentaerythritol tetra-acrylate (PETEA) with 1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane (Luperox 231®) as an initiator were studied and compared to the results obtained by IR imaging.

pH wave-front propagation in the urea-urease reaction.

The urease-catalyzed hydrolysis of urea displays feedback that results in a switch from acid (pH ~3) to base (pH ~9) after a controllable period of time (from 10 to >5000 s). Here we show that the spatially distributed reaction can support pH wave fronts propagating with a speed of the order of 0.1-1 mm min(-1).