Reagentless Dissolution and Quantification of Particulate Lead in Tap Water via Membrane Electrolysis.

The presence of particulate Pb in tap water has been a limiting factor in the design of accurate and portable platforms for quantifying this toxic metal. Convenient and affordable electrochemical techniques are blind toward particulate species and thus require addition of reagents and additional chemical processing such as sample acidification. This study describes the fundamentals and the first use of membrane electrolysis for the reagentless sample preparation of tap water for the detection of particulate Pb contaminants.

Impact of physical and chemical parameters on square wave anodic stripping voltammetry for trace Pb detection in water.

Exposure to lead, a toxic heavy metal, in drinking water is a worldwide problem. Lead leaching from lead service lines, the main contamination source, and other plumbing materials is controlled by the plumbosolvency of water. Square wave anodic stripping voltammetry (SWASV) has been greatly explored as a rapid and portable technique for the detection of trace Pb ions in drinking water.

Near-electrode pH change for voltammetric detection of insoluble lead carbonate.

Lead contamination of drinking water is a concern to all inhabitants of old cities where lead pipes and soldering are still present. Simple on-site electrochemical detection methods are promising technologies that have gained attention recently. However, conventional electrochemical techniques only quantify soluble forms of lead in water without accounting for insoluble particulates.