Preparation and structural characterization of (Me(3)SiNSN)(2)Se, a new synthon for sulfur-selenium nitrides.

The reaction of (Me(3)SiN)(2)S with SeCl(2) (2:1 ratio) in CH(2)Cl(2) at -70 degrees C provides a route to the novel mixed selenium-sulfur-nitrogen compound (Me(3)SiNSN)(2)Se (1). Crystals of 1 are monoclinic and belong the space group P2(1)/c, with a = 7.236(1) A, b = 19.

Preparation, X-ray Structure, and Spectroscopic Characterization of 1,5-Se(2)S(2)N(4).

The reaction of [(Me(3)Si)(2)N](2)S with equimolar amounts of SCl(2) and SO(2)Cl(2) produces S(4)N(4) in a good yield. The new chalcogen nitride 1,5-Se(2)S(2)N(4) has been prepared in high yield by two different reactions: (a) from [(Me(3)Si)(2)N](2)S and SeCl(4) and (b) from [(Me(3)Si)(2)N](2)Se with equimolar amounts of SCl(2) and SO(2)Cl(2). 1,5-Se(2)S(2)N(4) has a cage structure similar to those of S(4)N(4) and Se(4)N(4).

Theoretical and Experimental Studies of Six-Membered Selenium-Sulfur Nitrides Se(x)()S(4)(-)(x)()N(2) (x = 0-4). Preparation of S(4)N(2) and SeS(3)N(2) by the Reaction of Bis[bis(trimethylsilyl)amino]sulfane with Chalcogen Chlorides.

The reaction of [(Me(3)Si)(2)N](2)S with equimolar amounts of SCl(2) and S(2)Cl(2) produces S(4)N(2) in a good yield. The reaction of [(Me(3)Si)(2)N](2)S with a 3:1:1 mixture of S(2)Cl(2), Se(2)Cl(2), and SeCl(4) yields a dark brown-red insoluble material that was inferred to be mainly SSeSNSN on the basis of the elemental analysis, mass spectroscopy, vibrational analysis, and NMR spectroscopy. Attempts to prepare selenium-rich species resulted in the formation of elemental selenium or Se(3)N(2)Cl(2).