Chemical modification of graphene characterized by Raman and transport experiments.

A chemical approach to modify the electronic transport of graphene is investigated by detailed transport and Raman spectroscopy measurements on Hall bar shaped samples. The functionalization of graphene with nitrobenzene diazonium ions results in a strong p-doping of the graphene samples and only slightly lower mobilities. Comparing Raman and transport data taken after each functionalization step allowed the conclusion that two preferential reactions take place on the graphene surface.

Selective chemical modification of graphene surfaces: distinction between single- and bilayer graphene.

Graphene modifications with oxygen or hydrogen are well known in contrast to carbon attachment to the graphene lattice. The chemical modification of graphene sheets with aromatic diazonium ions (carbon attachment) is analyzed by confocal Raman spectroscopy. The temporal and spatial evolution of surface-adsorbed species allows accurate tracking of the chemical reaction and identification of intermediates.