Distribution and relationship of uranium and radium along an allochthonously dominated wetland gradient.

Uranium mining may pose a large threat for freshwater ecosystems, caused by elevated concentrations of metals/radionuclides in drainage water. Important pollutants of such waters are uranium (U) and radium (Ra), because of their impact due to both radio- as well as chemo-toxicity. Despite the comprehensive knowledge about specific element speciation as well as fixation processes, less is known about the retention of U and Ra at a higher level of complexity (within allochthonous ecosystems as predominant for low order streams).

Thunderbolt in biogeochemistry: galvanic effects of lightning as another source for metal remobilization.

Iron and manganese are relevant constituents of the earth's crust and both show increasing mobility when reduced by free electrons. This reduction is known to be controlled by microbial dissimilation processes. Alternative sources of free electrons in nature are cloud-to-ground lightning events with thermal and galvanic effects.

High mobilization of arsenic, metals and rare earth elements in seepage waters driven by respiration of old allochthonous organic carbon.

Metal and metalloid mobilization processes within seepage water are of major concern in a range of water reservoir systems. The mobilization process of arsenic and heavy metals within a dam and sediments of a drinking water reservoir was investigated. Principle component analysis (PCA) on time series data of seepage water showed a clear positive correlation of arsenic with iron and DOC (dissolved organic carbon), and a negative correlation with nitrate due to respiratory processes.

Changes in catchment conditions lead to enhanced remobilization of arsenic in a water reservoir.

Increasing arsenic concentrations in freshwater ecosystems is of global concern. Processes affecting arsenic fluxes in catchments are known. These processes are in turn controlled by the underlying geology and air pollution history.

Effects of gamma-sterilization on DOC, uranium and arsenic remobilization from organic and microbial rich stream sediments.

Organic-rich sediments are known to be effective accumulators for uranium and arsenic. Much is known about the capacity for metal or metalloid fixation by microbes and organic compounds as well as inorganic sediment particles. Experiments investigating the effect of microbes on the process of metal fixation in sediments require sterilized sediments as control treatment which is often realized by gamma-sterilization.

Invertebrates control metals and arsenic sequestration as ecosystem engineers.

Organic sediments are known to be a significant sink of inorganic elements in polluted freshwater ecosystems. Hence, we investigated the role of invertebrate shredders (the freshwater shrimp Gammarus pulex L.) in metal and arsenic enrichment into organic partitions of sediments in a wetland stream at former uranium mining site.

Enrichment of uranium in particulate matter during litter decomposition affected by Gammarus pulex L.

Plant litter and organic matter of aquatic sediments provide a significant sink of soluble inorganic uranium species in contaminated ecosystems. The uranium content in detritus has been observed to increase significantly during decomposition. However, the influence of the decomposer community on uranium fixation remains unclear.