Natural gas vaporization in a nanoscale throat connected model of shale: multi-scale, multi-component and multi-phase.

Production of hydrocarbons from shale is a complex process that necessitates the extraction of multi-component hydrocarbons trapped in multi-scale nanopores. While advances in nanofluidics have allowed researchers to probe thermodynamics and transport in single, discrete nanochannels, these studies present a highly simplified version of shale reservoirs with homogeneous pore structures and/or single-component fluid compositions. In this study, we develop and apply a 30 000-pore nanomodel that captures the inherent heterogeneity in reservoir pore sizes (100 nm pores gated by 5 nm-pores) to study vaporization of a representative natural gas hydrocarbon mixture.

Bubble nucleation and growth in nanochannels.

We apply micro- and nanofluidics to study fundamental phase change behaviour at nanoscales, as relevant to shale gas/oil production. We investigate hydrocarbon phase transition in sub-100 nm channels under conditions that mimic the pressure drawdown process. Measured cavitation pressures are compared with those predicted from the nucleation theory.