Semantic Annotation of Experimental Methods in Analytical Chemistry.

A major obstacle for reusing and integrating existing data is finding the data that is most relevant in a given context. The primary metadata resource is the scientific literature describing the experiments that produced the data. To stimulate the development of natural language processing methods for extracting this information from articles, we have manually annotated 100 recent open access publications in Analytical Chemistry as semantic graphs.

Electrochemical Properties of Nitrate-Selective Electrodes: The Dependence of Resistance on the Solution Concentration.

The electrochemical properties of ion-exchanger-based solvent polymeric ion-selective electrodes (ISEs)—bulk and interfacial resistance, capacitance, and polarization under a galvanostatic current step—are studied, with a nitrate ISE based on tetradecylammonium nitrate (TDANO₃) as a model system. The study is performed by chronopotentiometric and impedance measurements, and focuses on the dependence of the aforementioned properties on the concentration of NO₃ anions in solution. The impacts from the bulk and the interfacial charge transfer to the overall membrane resistance are revealed.