Densities, Viscosities of Pure 1-(2-Hydroxyethyl) Pyrrolidine, 3-Amino-1-Propanol, Water, and Their Mixtures at 293.15 to 363.15 K and Atmospheric Pressure.

Densities and viscosities of pure 1-(2-hydroxyethyl) pyrrolidine, 3-amino-1-propanol, water, and their blends' data are reported from 293.15 to 363.15 K and at ambient pressure.

Vapor-Liquid Equilibria Data for 2-Piperidineethanol and 1-(2-Hydroxyethyl)pyrrolidine in Aqueous Solutions and a UNIQUAC Model Representation.

This work reports equilibrium data for two amines, 2-piperidineethanol (2-PPE) and 1-(2-hydroxyethyl)pyrrolidine (1-(2HE)PRLD), and their aqueous solutions. The pressure, temperature, and composition data are used to calculate experimental activities. Data cover temperatures from 363 to 426 K for the pure amines and from 323 to 373 K for the aqueous solutions.

Theoretical study of differential enthalpy of absorption of CO2 with MEA and MDEA as a function of temperature.

Temperature dependent correlations for enthalpy of deprotonation, carbamate formation, and heat of absorption of the overall reaction between aqueous MEA and MDEA and gaseous CO2 are calculated on the basis of computational chemistry based ln K values input to the Gibbs-Helmholtz equation. Temperature dependency of reaction equilibrium constants for deprotonation and carbamate formation reactions is calculated with the SM8T continuum solvation model coupled with density functional theoretical calculations at the B3LYP/6-311++G(d,p) level of theory. Calculated reaction equilibrium constants and enthalpies of individual reactions and overall heat of absorption are compared against experimental data in the temperature range 273.