Effect of defects on the intrinsic strength and stiffness of graphene.

It is important from a fundamental standpoint and for practical applications to understand how the mechanical properties of graphene are influenced by defects. Here we report that the two-dimensional elastic modulus of graphene is maintained even at a high density of sp(3)-type defects. Moreover, the breaking strength of defective graphene is only ~14% smaller than its pristine counterpart in the sp(3)-defect regime.

Synergy derived by combining graphene and carbon nanotubes as nanofillers in composites.

Both one-dimensional carbon nanotubes as well as two-dimensional graphene sheets have been extensively investigated as nanofillers in composites. However there are very few reports on their combined use in composite materials. Here we report the mechanical properties including Young's modulus, tensile strength and fatigue properties of an epoxy polymer reinforced with various combinations of graphene and carbon nanotube fillers- i.

Control of epoxy creep using graphene.

The creep behavior of epoxy-graphene platelet (GPL) nanocomposites with different weight fractions of filler is investigated by macroscopic testing and nanoindentation. No difference is observed at low stress and ambient temperature between neat epoxy and nanocomposites. At elevated stress and temperature the nanocomposite with the optimal weight fraction, 0.

Graphene nanoribbon composites.

It is well established that pristine multiwalled carbon nanotubes offer poor structural reinforcement in epoxy-based composites. There are several reasons for this which include reduced interfacial contact area since the outermost nanotube shields the internal tubes from the matrix, poor wetting and interfacial adhesion with the heavily cross-linked epoxy chains, and intertube slip within the concentric nanotube cylinders leading to a sword-in-sheath type failure. Here we demonstrate that unzipping such multiwalled carbon nanotubes into graphene nanoribbons results in a significant improvement in load transfer effectiveness.