Formation of Nanofibrous Structure in Biopolymer Aerogel during Supercritical CO Processing: The Case of Chitosan Aerogel.

Supercritical drying is widely considered as the gold standard to produce aerogels that preserve the microstructure of the gels, but we have found this is not always the case. Chitosan aerogel, one of the emerging biopolymer aerogels, was prepared by chemical cross-linking gelation, followed by solvent exchange with methanol and supercritical drying using CO. Small-angle X-ray scattering analysis shows that the structure of the wet gel, which consists of Gaussian chains of individual molecular strands, converts into a nanofibrous network during CO processing.

Aldehyde Approach to Hydrophobic Modification of Chitosan Aerogels.

Biobased nanofiber aerogels are ones of the attractive emerging materials in the fields of biochemistry and materials chemistry, but their poor humidity stability due to high hydrophilicity has limited their practical uses. In this paper, a new series of hydrophobic nanofibrous aerogels made from regenerated chitosan and alkyl aldehydes were prepared via a simple one-pot reaction followed by supercritical drying. Hexanal-modified chitosan aerogel shows excellent hydrophobicity with a water contact angle of ∼136°, a low density of 0.