Delayed emission from α-terthiophene (3T) and α-quinquethiophene (5T) in a perhydrotriphenylene (PHTP) host is investigated. Delayed fluorescence for the lowest singlet excited state of 3T and 5T is detected at both low (80 K) and room temperatures. In addition, at low temperature, phosphorescence from 3T is observed with a lifetime of ∼100 μs.
View Article and Find Full Text PDFThe W-band continuous-wave electron paramagnetic resonance (EPR) analysis of chemically induced polarons in drop-cast and spin-coated polyphenylenevinylene-type and polythiophene-type polymer films reveals rhombic g tensors in both cases. The dependence of the W-band EPR signals on the orientation of the spin-coated films with respect to the magnetic field indicates a high degree of backbone alignment with the substrate and allows a partial assignment of the g tensor orientation. The derived molecular orientations of the polymer chains in the spin-coated films show clear differences between the two types of polymers.
View Article and Find Full Text PDF