Magnetically Propelled Microrobots toward Photosynthesis of Green Ammonia from Nitrates.

Ammonia (NH₃) production is a critical industrial process, as ammonia is a key component in fertilizers, essential for global agriculture and food production. However, the current method of synthesizing ammonia, the Haber-Bosch process, is highly energy-intensive, and relies on fossil fuels, contributing substantially to greenhouse gas emissions. Moreover, the centralized nature of the Haber-Bosch process limits its accessibility in remote or resource-limited areas.

Direct realization of an Operando Systems Chemistry Algorithm (OSCAL) for powering nanomotors.

Systems chemistry focuses on emergent properties in a complex matter. To design and demonstrate such emergent properties like autonomous motion in nanomotors as an output of an Operando Systems Chemistry Algorithm (OSCAL), we employ a 2-component system comprising porous organic frameworks (POFs) and soft-oxometalates (SOMs). The OSCAL governs the motion of the nanocarpets by the coding and reading of information in an assembly/disassembly cascade switched on by a chemical stimulus.

Visible light driven catalytic gold decorated soft-oxometalate (SOM) based nanomotors for organic pollutant remediation.

Visible light propelled nanomotors are a class of highly sought after active matter. Here we report a gold decorated semiconductor and a soft-oxometalate based TiO2-{Mo7}-Au nanomotor which can be propelled diffusiophoretically on exposure to visible light and show excellent photocatalytic activity. These systems exclude the use of any harsh toxic chemical as fuel and exhibit a speed of 10 μm s-1 in water.

Redox Reaction Triggered Nanomotors Based on Soft-Oxometalates With High and Sustained Motility.

The recent interest in self-propulsion raises an immediate challenge in facile and single-step synthesis of active particles. Here, we address this challenge and synthesize soft oxometalate nanomotors that translate ballistically in water using the energy released in a redox reaction of hydrazine fuel with the soft-oxometalates. Our motors reach a maximum speed of 370 body lengths per second and remain motile over a period of approximately 3 days.