Crosslinking of Epoxidized Natural Rubber with Borax for Self-Healing and Self-Repairing Properties: pH Dependence.

Epoxidized natural rubber (ENR) crosslinked using borax, which exhibits self-healing and self-repairing properties, is successfully developed. The crosslink formation of ENR by using borax under neutral and alkaline conditions is investigated. Fourier transform infrared spectroscopy (FTIR) shows that the borate-ester bond is formed in ENR prepared under both neutral and alkaline conditions, whereas boron nuclear magnetic resonance ( B-NMR) results exhibit that the ENR prepared under alkaline conditions more actively forms crosslink networks with borax.

Development of water-resistant paper using chitosan and plant-based wax extracted from banana leaves.

On being exposed to water, cellulose paper swells and its mechanical properties become weak. In this study, natural wax with an average particle size of 12.3 μm extracted from banana leaves was mixed with chitosan to prepare coatings applied on paper surfaces.

Property enhancement of epoxidized natural rubber nanocomposites with water hyacinth-extracted cellulose nanofibers.

Cellulose nanofibers (CNFs) have been widely used as reinforcement in various polymer matrices; however, limited studies of the use of CNFs in epoxidized natural rubber (ENR) have been reported. Here, we successfully prepared CNF-reinforced ENR nanocomposites with superior mechanical performance. CNFs were disintegrated from water hyacinth (Eichhornia crassipes) using high-pressure homogenization, and ENR nanocomposites with CNFs were fabricated by initial mixing and hot pressing.

Superabsorbent cellulose-based hydrogels cross-liked with borax.

Cellulose, the most abundant biopolymer on Earth, has been widely attracted owing to availability, intoxicity, and biodegradability. Environmentally friendly hydrogels were successfully prepared from water hyacinth-extracted cellulose using a dissolution approach with sodium hydroxide and urea, and sodium tetraborate decahydrate (borax) was used to generate cross-linking between hydroxyl groups of cellulose chains. The incorporation of borax could provide the superabsorbent feature into the cellulose hydrogels.

Review of the recent developments in all-cellulose nanocomposites: Properties and applications.

Cellulose, the most abundant polysaccharide on Earth, has a number of desirable properties, including availability, biodegradability, low cost, and low toxicity and has been used in a variety of applications. Recently, all-cellulose composite materials have been made from a wide variety of cellulose sources, including wood and agricultural wastes, via impregnation or partial surface dissolution approaches utilizing a specific solvent. Due to the improved interfacial interactions between the cellulose matrix and cellulose reinforcement, all-cellulose composites exhibit superior mechanical properties when compared to biopolymers and petroleum-based polymers.