Adhesion and Contact Aging of Acrylic Pressure-Sensitive Adhesives to Swollen Elastomers.

Fluid-infused (or swollen) elastomers are known for their antiadhesive properties. The presence of excess fluid at their surface is the main contributor to limiting contact formation and minimizing adhesion. Despite their potential, the mechanisms for adhesion and contact aging to fluid-infused elastomers are poorly understood beyond contact with a few materials (ice, biofilms, glass).

Interface Stabilization in Adhesion Caused by Elastohydrodynamic Deformation.

Interfacial instabilities are common phenomena observed during adhesion measurements involving viscoelastic polymers or fluids. Typical probe-tack adhesion measurements with soft adhesives are conducted with rigid probes. However, in many settings, such as for medical applications, adhesives make and break contact from soft surfaces such as skin.

Adhesion of fluid infused silicone elastomer to glass.

Elastomers swollen with non-polar fluids show potential as anti-adhesive materials. We study the effect of oil fraction and contact time on the adhesion between swollen spherical probes of PDMS (polydimethylsiloxane) and flat glass surfaces. The PDMS probes are swollen with pre-determined amount of 10 cSt silicone oil to span the range where the PDMS is fluid free ( solvent extraction) up to the limit where it is oil saturated.

Contribution of Surface Energy to pH-Dependent Underwater Adhesion of an Acrylic Pressure-Sensitive Adhesive.

Maintaining the underwater adhesive performance over a broad range of solution pH is challenging but necessary for many biomedical applications. Therefore, understanding how environmental conditions influence the mechanisms of bonding and debonding of pressure-sensitive adhesives (PSAs) can provide guidelines for materials design. We investigate how the presence of acrylic acid as a co-monomer impacts the adhesion of a model PSA in aqueous environments of varying pH.