The influence of the acid sites in the hydrodeoxygenation of anisole performed over Ni catalysts supported on SBA-15 modified with metal oxides (Ni/M-SBA-15, M = Ti, Zr, Al, or Nb) was demonstrated. Catalysts were characterized by SEM-EDX, nitrogen physisorption, XRD, UV-visible DRS, TPR, TPD of ammonia, IR-Py, O chemisorption, and high-resolution transmission electron microscopy. The mesoporous structure and the hexagonal arrangement of the supports were maintained in the catalysts.
View Article and Find Full Text PDFNickel (5 wt%) supported on Nd-doped ceria was studied as catalysts in the DRM reaction at stoichiometric conditions in the range of 600-800 °C. Ce Nd O supports with different Nd contents ( = 0, 0.05, 0.
View Article and Find Full Text PDFThe enhancement of CO capture due to the confinement of polar molecules within InOF-1 was previously demonstrated. In particular, the presence of MeOH produced 1.30-fold increase in the total CO capture.
View Article and Find Full Text PDFThe effect of the use of the triblock copolymer Pluronic P123[(PEO)(PPO)(PEO), Aldrich] and the non-ionic polyoxyethylene-lauryl ether Brij 35 as surfactants on the textural, structural and electrical properties of nanosized TiO is analyzed in this work. The as-obtained samples were thermally treated at 400 °C to eliminate the surfactant, promote dehydroxylation and crystallize the sample. The TiO samples were characterized by thermal analysis, N physisorption, x-ray diffraction analysis, micro-Raman spectroscopy and scanning electron microscopy.
View Article and Find Full Text PDFThe surface properties of bimetallic Ni-Pt/SiO2 catalysts with variable Ni/Ni + Pt atomic ratio (0.75, 0.50, and 0.
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