Publications by authors named "Anton S Ganin"
The reactions of alkenes with phenyl--triflylimino-λ-iodane PhI=NTf () have been studied in different conditions. In methylene chloride, in the presence of -halosuccinimides, the products of mono and bis-triflamidation were obtained. In MeCN, the product of bromotriflamidation (with NBS) with solvent interception or of bis-triflamidation (with NIS) is formed.
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- - Allyl halides react with triflamide under oxidative conditions to create halogen-substituted amidines.
- - Allyl cyanide reacts with triflamide in acetonitrile or THF with NBS, producing bromotriflamidation products; different solvents yield different regioisomers.
- - The resulting products can undergo dehydrobromination to form linear isomers with new C=C bonds, and bromo-substituted amidines can transform into imidazolidines with potassium carbonate.