Publications by authors named "Anthony R J Kucernak"

A hydrogen-organic hybrid flow battery (FB) has been developed using methylene blue (MB) in an aqueous acid electrolyte with a theoretical positive electrolyte energy storage capacity of 65.4 A h L. MB paired with the versatile H/H redox couple at the negative electrode forms the H-MB rechargeable fuel cell, with no loss in capacity (5 sig.

View Article and Find Full Text PDF
Article Synopsis
  • The crystal phase of two-dimensional transition-metal dichalcogenides (TMDs) significantly impacts their properties and functionalities, especially in applications like catalysis.
  • The study found that MoS nanosheets with a pure 2H phase enhance the growth of Pt nanoparticles, while the 1T' phase supports single-atom Pt catalysts, impacting their electrocatalytic performance.
  • Results demonstrate that the s-Pt/1T'-MoS system shows promising electrocatalytic activity for hydrogen evolution in acidic media, indicating its potential for future catalytic applications, despite limitations in high-temperature operations.
View Article and Find Full Text PDF

There are a number of critical requirements for electrolytes in aqueous redox flow batteries. This paper reviews organic molecules that have been used as the redox-active electrolyte for the positive cell reaction in aqueous redox flow batteries. These organic compounds are centred around different organic redox-active moieties such as the aminoxyl radical (TEMPO and N-hydroxyphthalimide), carbonyl (quinones and biphenols), amine (e.

View Article and Find Full Text PDF

A simple, modified Metal-Organic Chemical Deposition (MOCD) method for Pt, PtRu and PtCo nanoparticle deposition onto a variety of support materials, including C, SiC, BC, LaB, TiB, TiN and a ceramic/carbon nanofiber, is described. Pt deposition using Pt(acac) as a precursor is shown to occur a mixed solid/liquid/vapour precursor phase which results in a high Pt yield of 90-92% on the support material. Pt and Pt alloy nanoparticles range 1.

View Article and Find Full Text PDF

Tuning the properties of optical metamaterials in real time is one of the grand challenges of photonics. Being able to do so will enable a class of adaptive photonic materials for use in applications such as surface enhanced Raman spectroscopy and reflectors/absorbers. One strategy to achieving this goal is based on the electrovariable self-assembly and disassembly of two-dimensional nanoparticle arrays at a metal | liquid interface.

View Article and Find Full Text PDF

Electrowetting-on-dielectric devices typically have operating voltages of 10-20 V. A reduction in the operating voltage could greatly reduce the energy consumption of these devices. Herein, fully reversible one-electrolyte electrowetting of a droplet on a solid metal surface is reported for the first time.

View Article and Find Full Text PDF

This paper addresses the challenge of producing multifunctional composites that can simultaneously carry mechanical loads whilst storing (and delivering) electrical energy. The embodiment is a structural supercapacitor built around laminated structural carbon fibre (CF) fabrics. Each cell consists of two modified structural CF fabric electrodes, separated by a structural glass fibre fabric or polymer membrane, infused with a multifunctional polymeric electrolyte.

View Article and Find Full Text PDF