Hydrothermal reaction of a macrocyclic inorganic POM cavitand Li(NH)H[PWO] with [Pt(HO)(OH)] results in coordination of up to six {Pt(HO)(OH)} fragments to the internal surface of the polyoxoanion. The product was isolated as K(NH)H[{Pt(OH)(HO)}PWO]·79HO () and characterized by multiple techniques in the solid state (SCXRD, XRPD, XPS, FTIR, and TGA) and in solution (NMR, ESI-MS, and HPLC-ICP-AES). Electrochemical properties were studied both in solution and as components of the paste electrode.
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