Adding silicon (Si) to graphite (Gr) anodes is an effective approach for boosting the energy density of lithium-ion batteries, but it also triggers mechanical instability due to Si volume changes upon (de)lithiation reactions. In this work, component-specific (de)lithiation dynamics on Si-rich (30 and 70 wt.% Si) SiGr anodes at various charge/discharge C-rates are unveiled and compared to a graphite-only electrode (100Gr) via operando synchrotron X-ray diffraction coupled with differential capacity plots analysis.
View Article and Find Full Text PDFBackground: Few studies consider both radiological and functional outcomes in COVID-19 survivors treated in the intensive care unit (ICU). We investigated clinical findings and pulmonary abnormalities on chest computed tomography (CT) and compared outcomes of severe versus mild-moderate acute respiratory distress syndrome (ARDS) on long-term follow-up.
Methods: This longitudinal cohort study included 118 COVID-19 patients (median age, 58 years; 79% men).
[Formula: see text] is a promising material for developing high-capacity anodes for lithium-ion batteries (LIBs). However, microstructural changes of [Formula: see text] anodes at the particle and electrode level upon prolonged cycling remains unclear. In this work, the causes leading to capacity fade on [Formula: see text] anodes were investigated and simple strategies to attenuate anode degradation were explored.
View Article and Find Full Text PDFInterstitial lung disease can be the first sign of systemic autoimmune disease. If associated with myositis, interstitial lung disease may be the only symptom, with no presence of muscular weakness or other extramuscular manifestations. ANA-testing performed with indirect immune fluorescence may be negative.
View Article and Find Full Text PDFTiO -coating of LiNi Mn O (LNMO) by atomic layer deposition (ALD) has been studied as a strategy to stabilize the cathode/electrolyte interface and mitigate transition metal (TM) ion dissolution. The TiO coatings were found to be uniform, with thicknesses estimated to 0.2, 0.
View Article and Find Full Text PDFThis study demonstrates the application of AlO coatings for the high-voltage cathode material LiNi Mn O (LNMO) by atomic layer deposition. The ultrathin and uniform coatings (0.6-1.
View Article and Find Full Text PDFBackground: Kidney disease and renal failure are associated with hospital deaths in patients with COVID - 19. We aimed to test if contrast enhancement affects short-term renal function in hospitalized COVID - 19 patients.
Methods: Plasma creatinine (P-creatinine) was measured on the day of computed tomography (CT) and 24 h, 48 h, and 4-10 days after CT.
Severe COVID-19 is associated with inflammation, thromboembolic disease, and high mortality. We studied factors associated with fatal outcomes in consecutive COVID-19 patients examined by computed tomography pulmonary angiogram (CTPA). This retrospective, single-center cohort analysis included 130 PCR-positive patients hospitalized for COVID-19 [35 women and 95 men, median age 57 years (interquartile range 51-64)] with suspected pulmonary embolism based on clinical suspicion.
View Article and Find Full Text PDFDiatomaceous earth (DE) is a naturally occurring silica source constituted by fossilized remains of diatoms, a type of hard-shelled algae, which exhibits a complex hierarchically nanostructured porous silica network. In this work, we analyze the positive effects of reducing DE SiO particles to the sub-micrometer level and implementing an optimized carbon coating treatment to obtain DE SiO anodes with superior electrochemical performance for Li-ion batteries. Pristine DE with an average particle size of 17 μm is able to deliver a specific capacity of 575 mA h g after 100 cycles at a constant current of 100 mA g, and reducing the particle size to 470 nm enhanced the reversible specific capacity to 740 mA h g.
View Article and Find Full Text PDFSilicon, while suffering from major degradation issues, has been recognized as a next promising material to replace currently used graphite in the anodes of Li-ion batteries. Several pathways to mitigate the capacity fading of silicon has been proposed, including optimization of the electrode composition. Within the present work we evaluated different binder formulations to improve the long-term performance of the Li-ion batteries' anodes based on industrial grade silicon (Si) which is typically characterized by a particle sizes ranging from 100 nm to 5.
View Article and Find Full Text PDFWe here describe the current knowledge about the radiologic and histologic pulmonary features of covid-19, caused by SARS-CoV-2, and present lung histology from a case with fatal disease. Initial findings on computed tomography (CT) typically include peripheral multifocal bilateral ground-glass opacities, and correspondingly microscopic alveolar edema. This is followed by peripheral consolidations with air bronchogram and perilobular pattern on CT, signs of organizing pneumonia, corresponding to loose (potentially reversible) fibrosis.
View Article and Find Full Text PDFIn spite of its insulating nature, SiO may be utilized as active anode material for Li-ion batteries. Synthetic SiO will typically require sophisticated synthesis and/or activation procedures in order to obtain a satisfactory performance. Here, we report on diatom frustules as active anode material without the need for extensive activation procedures.
View Article and Find Full Text PDFA rechargeable Mg battery where the capacity mainly originates from reversible reactions occurring at the electrode/electrolyte interface efficiently avoids the challenge of sluggish Mg intercalation encountered in conventional Mg batteries. The interfacial reactions in a cell based on microwave-exfoliated graphite oxide (MEGO) as the cathode and all phenyl complex (APC) as electrolyte are identified by quantitative kinetics analysis as a combination of diffusion-controlled reactions involving ether solvents ( esols) and capacitive processes. During magnesiation, esols in APC electrolytes can significantly affect the electrochemical reactions and charge transfer resistances at the electrode/electrolyte interface and thus govern the charge storage properties of the MEGO cathode.
View Article and Find Full Text PDFConsidering the improved safety, reduced cost, and high volumetric energy density associated with Mg batteries, this technology has distinct advantages for large-scale energy storage compared to other existing battery technologies. However, the divalency of the Mg cation cause sluggish magnesiation kinetics in crystalline host materials, resulting in poor performance with regards to capacity and cycling stability for intercalation based electrodes. Here, we present a Mg battery using MnO as the electrode material and Mg metal as the counter electrode in a Mg organohaloaluminate electrolyte.
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