Self-assembly of polyhedral-shaped particles has attracted huge interest with the advent of new synthesis methods that realize these faceted particles in the lab. Recent studies have shown that polyhedral-shaped particles exhibit a rich phase behavior by excluded volume interactions alone; some of these particles are even alleged to show a transition to a glass phase by quenching the liquid sufficiently fast beyond the glass transition (supercooling), such that the formation of structures with long-range order is suppressed. Despite the recent progress, no study has been made on the glass formation of polyhedral-shaped particles.
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