The optical properties of MoS and WS monolayers are significantly influenced by fabrication methods, especially with respect to the behavior of excitons at the -point of the Brillouin zone. Using spectroscopic ellipsometry, we obtain the complex dielectric functions of monolayers of these materials from cryogenic to room temperatures over the energy range 1.5 to 6.
View Article and Find Full Text PDFIntracranial implants for diagnosis and treatment of brain diseases have been developed over the past few decades. However, the platform of conventional implantable devices still relies on invasive probes and bulky sensors in conjunction with large-area craniotomy and provides only limited biometric information. Here, an implantable multi-modal sensor array that can be injected through a small hole in the skull and inherently spread out for conformal contact with the cortical surface is reported.
View Article and Find Full Text PDFIntegration of photovoltaic (PV) systems, desalination technologies, and Artificial Intelligence (AI) combined with Machine Learning (ML) has introduced a new era of remarkable research and innovation. This review article thoroughly examines the recent advancements in the field, focusing on the interplay between PV systems and water desalination within the framework of AI and ML applications, along with it analyses current research to identify significant patterns, obstacles, and prospects in this interdisciplinary field. Furthermore, review examines the incorporation of AI and ML methods in improving the performance of PV systems.
View Article and Find Full Text PDFStrain engineering has been employed as a crucial technique to enhance the electrical properties of semiconductors, especially in Si transistor technologies. Recent theoretical investigations have suggested that strain engineering can also markedly enhance the carrier mobility of two-dimensional (2D) transition-metal dichalcogenides (TMDs). The conventional methods used in strain engineering for Si and other bulk semiconductors are difficult to adapt to ultrathin 2D TMDs.
View Article and Find Full Text PDFUsing bone char for contaminated wastewater treatment and soil remediation is an intriguing approach to environmental management and an environmentally friendly way of recycling waste. The bone char remediation strategy for heavy metal-polluted wastewater was primarily affected by bone char characteristics, factors of solution, and heavy metal (HM) chemistry. Therefore, the optimal parameters of HM sorption by bone char depend on the research being performed.
View Article and Find Full Text PDFFlexible electronics have recently gained considerable attention due to their potential to provide new and innovative solutions to a wide range of challenges in various electronic fields. These electronics require specific material properties and performance because they need to be integrated into a variety of surfaces or folded and rolled for newly formatted electronics. Two-dimensional (2D) materials have emerged as promising candidates for flexible electronics due to their unique mechanical, electrical, and optical properties, as well as their compatibility with other materials, enabling the creation of various flexible electronic devices.
View Article and Find Full Text PDFThree-dimensional (3D) hetero-integration technology is poised to revolutionize the field of electronics by stacking functional layers vertically, thereby creating novel 3D circuity architectures with high integration density and unparalleled multifunctionality. However, the conventional 3D integration technique involves complex wafer processing and intricate interlayer wiring. Here we demonstrate monolithic 3D integration of two-dimensional, material-based artificial intelligence (AI)-processing hardware with ultimate integrability and multifunctionality.
View Article and Find Full Text PDFThe uniform deposition of perovskite light-emitting diodes (PeLEDs) and their integration with backplane thin-film transistors (TFTs) remain challenging for large-area display applications. Herein, an active-matrix PeLED display fabricated via the heterogeneous integration of cesium lead bromide LEDs and molybdenum disulfide (MoS )-based TFTs is presented. The single-source evaporation method enables the deposition of highly uniform perovskite thin films over large areas.
View Article and Find Full Text PDFThe growing concern over the presence of pollutants like Bisphenol A (BPA) in water sources has led to the growth of novel treatment technologies for its removal. This research work investigates the development of a novel biochar-metal oxide nanocomposite derived from tannery sludge and Zinc oxide (ZnO) nanoparticles for the photodegradation of BPA. The biochar was obtained by pyrolysis process, followed by impregnation of ZnO nanoparticles using a hydrothermal technique.
View Article and Find Full Text PDFP-values that are derived from continuously distributed test statistics are typically uniformly distributed on (0,1) under least favorable parameter configurations (LFCs) in the null hypothesis. Conservativeness of a p-value P (meaning that P is under the null hypothesis stochastically larger than uniform on (0,1)) can occur if the test statistic from which P is derived is discrete, or if the true parameter value under the null is not an LFC. To deal with both of these sources of conservativeness, we present two approaches utilizing randomized p-values.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2023
Advancements in the synthesis of large-area, high-quality two-dimensional transition metal dichalcogenides such as MoS play a crucial role in the development of future electronic and optoelectronic devices. The presence of defects formed by sulfur vacancies in MoS results in low photoluminescence emission and imparts high n-type doping behavior, thus substantially affecting material quality. Herein, we report a new method in which single-phase (liquid) precursors are used for the metal-organic chemical vapor deposition (MOCVD) growth of a MoS film.
View Article and Find Full Text PDFBiochar is widely used to remove organic pollutants from the environment. Several studies have focused on pollutant removal via biochar adsorption. However, research on the subsequent processing of pollutant-adsorbed biochar is lacking.
View Article and Find Full Text PDFTitanium dioxide (Titania) nanoparticle-coated biochar derived through co-pyrolysis of COVID-19 waste face mask (WFM) and Moringa oleifera seed cake (MO) provides an effective way to alleviate toxic metal in wastewater. This study investigates the effects of Biochar/titania photocatalyst preparation, characterization, and its photoreduction of Cr(VI). The morphological and functional modifications in the catalyst were identified using X-Ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, ultraviolet spectrophotometer, surface area analysis, and Raman spectrophotometer, respectively.
View Article and Find Full Text PDFRecent advances in two-dimensional semiconductors, particularly molybdenum disulfide (MoS), have enabled the fabrication of flexible electronic devices with outstanding mechanical flexibility. Previous approaches typically involved the synthesis of MoS on a rigid substrate at a high temperature followed by the transfer to a flexible substrate onto which the device is fabricated. A recurring drawback with this methodology is the fact that flexible substrates have a lower melting temperature than the MoS growth process, and that the transfer process degrades the electronic properties of MoS.
View Article and Find Full Text PDFThe biorefining process of lignocellulosic biomass has recently emerged as one of the most profitable biofuel production options. However, pretreatment is required to improve the recalcitrant lignocellulose's enzymatic conversion efficiency. Among biomass pretreatment methods, the steam explosion is an eco-friendly, inexpensive, and effective approach to pretreating biomass, significantly promoting biofuel production efficiency and yield.
View Article and Find Full Text PDFAnthropogenic emissions of CO have reached a critical level and the global surface temperature is expected to rise by 1.5 °C between 2030 and 2050. To ameliorate the current global warming scenario, the research community has been struggling to find more economical and innovative solutions for carbon sequestration.
View Article and Find Full Text PDFFood waste (FW) is a severe environmental and social concern that today's civilization is facing. Therefore, it is necessary to have an efficient and sustainable solution for managing FW bioprocessing. Emerging technologies like the Internet of Things (IoT), Artificial Intelligence (AI), and Machine Learning (ML) are critical to achieving this, in which IoT sensors' data is analyzed using AI and ML techniques, enabling real-time decision-making and process optimization.
View Article and Find Full Text PDFMicroalgae have great potential in producing energy-dense and valuable products via thermochemical processes. Therefore, producing alternative bio-oil to fossil fuel from microalgae has rapidly gained popularity due to its environmentally friendly process and elevated productivity. This current work aims to review comprehensively the microalgae bio-oil production using pyrolysis and hydrothermal liquefaction.
View Article and Find Full Text PDFBiowaste remediation and valorization for environmental sustainability focuses on prevention rather than cleanup of waste generation by applying the fundamental recovery concept through biowaste-to-bioenergy conversion systems - an appropriate approach in a circular bioeconomy. Biomass waste (biowaste) is discarded organic materials made of biomass (e.g.
View Article and Find Full Text PDF(1) Background and Goal: Several studies have investigated the association of sleep, diurnal patterns, and circadian rhythms with the presence and with the risk states of mental illnesses such as schizophrenia and bipolar disorder. The goal of our study was to examine actigraphic measures to identify features that can be extracted from them so that a machine learning model can detect premorbid latent liabilities for schizotypy and bipolarity. (2) Methods: Our team developed a small wrist-worn measurement device that collects and identifies actigraphic data based on an accelerometer.
View Article and Find Full Text PDFLarge-size woody biomass is a valuable renewable resource to replace fossil fuels in biorefinery processes. The preprocessing of wood chips and briquettes is challenging to manage, especially in an industrial setting, as it generates a significant amount of dust and noise and occasionally causes unexpected accidents. As a result, a substantial amount of resources, energy, labor, and space are needed.
View Article and Find Full Text PDFAnaerobic digestion (AD) is a viable and cost-effective method for converting organic waste into usable renewable energy. The efficiency of organic waste digestion, nonetheless, is limited due to inhibition and instability. Accordingly, biochar is an effective method for improving the efficiency of AD by adsorbing inhibitors, promoting biogas generation and methane concentration, maintaining process stability, colonizing microorganisms selectively, and mitigating the inhibition of volatile fatty acids and ammonia.
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