Biosensors Based on Acetylcholinesterase Immobilized on Clay-Gold Nanocomposites for the Discrimination of Chlorpyrifos and Carbaryl.

This work aims at evaluating a utilization of diverse clay mineral/gold nanoparticles/acetylcholinesterase (clay/AuNPs/AChE) biosensors by using principal component analysis (PCA) for the discrimination of pesticide types and their concentration levels both in the synthetic and real samples. Applications of simple and low-cost clay/AuNP composites of different characteristics as modified-electrode materials are highlighted. Four types of clay minerals, namely, platelike kaolinite (Kaol: 1:1 aluminum phyllosilicate), globular montmorillonite (Mt: 2:1 aluminum phyllosilicate), globular bentonite (Bent: 2:1 aluminum phyllosilicate), and fibrous sepiolite (Sep: 2:1 inverted ribbons of magnesium phyllosilicate), were selected as the base materials.