Detoxification of oil refining effluents by oxidation of naphthenic acids using TAML catalysts.

The environmental problem stemming from toxic and recalcitrant naphthenic acids (NAs) present in effluents from the oil industry is well characterized. However, despite the numerous technologies evaluated for their destruction, their up-scaling potential remains low due to high implementation and running costs. Catalysts can help cutting costs by achieving more efficient reactions with shorter operating times and lower reagent requirements.

Naphthenic acids are key contributors to toxicity of heavy oil refining effluents.

Oil refining produces vast quantities of wastewater with harmful contaminants that can be released back into the environment with a possible risk of toxicity to aquatic wildlife and human populations. Hence the importance of adequate wastewater treatment to achieve safe effluents that protect both ecological and human health. However, some refining effluents are linked to serious pollution problems even after treatment, partly because little progress has been made in determining the causative agents of the observed biological effects, resulting in non-targeted treatment.