Publications by authors named "Anette Eleonora Gunnaes"
In catalysts for CO hydrogenation, the interface between metal nanoparticles (NPs) and the support material is of high importance for the activity and reaction selectivity. In Pt NP-containing UiO Zr-metal-organic frameworks (MOFs), key intermediates in methanol formation are adsorbed at open Zr-sites at the Pt-MOF interface. In this study, we investigate the dynamic role of the Zr-node and the influence of HO on the CO hydrogenation reaction at 170 °C, through steady state and transient isotope exchange experiments, HO cofeed measurements, and density functional theory (DFT) calculations.
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- An all-oxide thermoelectric generator relies on a low electrical resistance at the p-n junction formed by p-type CaCoO and n-type CaMnO.
- Heat treatment at 900 °C for 10 hours leads to counter diffusion of cations and the formation of a CaCoMnO interlayer, as well as precipitation of Co-oxides.
- Density functional theory calculations confirm the variability of the Co/Mn ratio in the interlayer and suggest a homogeneity range for CaCoMnO with a low mixing energy.