Yb-Doped Silicate Glasses as Optical Sensor Materials for Cryogenic Thermometry.

Optical sensors constitute attractive alternatives to resistive probes for the sensing and monitoring of temperature (). In this work, we investigated, in the range from 2 to 300 K, the thermal behavior of Yb ion photoluminescence (PL) in glass hosts for cryogenic thermometry. To that end, two kinds of Yb-doped preforms, with aluminosilicate and aluminophosphosilicate core glasses, were made using the modified chemical vapor deposition (MCVD) technique.

All-fiber frequency agile triple-frequency comb light source.

Tricomb spectroscopy unveils a new dimension to standard linear and nonlinear spectroscopic analysis, offering the possibility to reveal the almost real-time evolution of complex systems with unprecedented accuracy. Current triple comb configurations are based on the use of mode-locked lasers, which impose constraints on the comb parameters, and require complex electronic synchronization, thus limiting potential applications. In this paper, we present the experimental demonstration of a new type of all-fiber, self-phase-locked, frequency-agile tri-comb light source.

Coupling optimized bending-insensitive multi-core fibers for lensless endoscopy.

We report a bending-insensitive multi-core fiber (MCF) for lensless endoscopy imaging with modified fiber geometry that enables optimal light coupling in and out of the individual cores. In a previously reported bending insensitive MCF (twisted MCF), the cores are twisted along the length of the MCF allowing for the development of flexible thin imaging endoscopes with potential applications in dynamic and freely moving experiments. However, for such twisted MCFs the cores are seen to have an optimum coupling angle which is proportional to their radial distance from the center of the MCF.

Few-mode erbium-doped fiber amplifier based on a multi-inclusions core optical fiber.

In this work, we demonstrate and evaluate a new design of micro-structured core erbium-doped few-mode fiber to be used as optical amplifier in the context of mode-division multiplexing. This concept is proposed so as to better control the distribution of the Er ions in the core area, thus permitting to adjust the overall differential modal gains between the different signal modes. The design presented here consists of 19 erbium-doped inclusions embedded in a pedestal geometry guiding 10 modes in the C-band.

All-solid polarization-maintaining silica fiber with birefringence induced by anisotropic metaglass.

We report the development of a silica glass single-mode polarization-maintaining fiber with birefringence induced by artificial anisotropic glass in the circular core without any external stress zones or structured cladding. The fiber core is composed of silica and germanium-doped silica nanorods ordered in submicrometer interleaved layers. The fiber has a measured cut-off wavelength at 1113 nm, phase birefringence of 0.

Investigation of the Incorporation of Cerium Ions in MCVD-Silica Glass Preforms for Remote Optical Fiber Radiation Dosimetry.

The incorporation of Ce ions in silicate glasses is a crucial issue for luminescence-based sensing applications. In this article, we report on silica glass preforms doped with cerium ions fabricated by modified chemical vapor deposition (MCVD) under different atmospheres in order to favor the Ce oxidation state. Structural analysis and photophysical investigations are performed on the obtained glass rods.

Cu/Ce-co-Doped Silica Glass as Radioluminescent Material for Ionizing Radiation Dosimetry.

Optically activated glasses are essential to the development of new radiation detection systems. In this study, a bulk glassy rod co-doped with Cu and Ce ions, was prepared via the sol-gel technique and was drawn at about 2000 °C into a cylindrical capillary rod to evaluate its optical and radioluminescence properties. The sample showed optical absorption and photoluminescence (PL) bands attributed to Cu and Ce ions.

Polarization-maintaining and single-mode large mode area pixelated Bragg fiber.

This Letter reports on a large mode area pixelated Bragg fiber in which some high refractive index rods were replaced by boron-doped rods that allows polarization maintaining behavior while keeping single-mode behavior. The realized all-solid fiber has a core diameter of 35 µm. The fundamental mode is circular with a 25 µm mode field diameter around 1 µm wavelength, and the polarization extinction ratio reaches 30 dB.

High-accuracy and high-sensitivity spectroscopic measurement of dinitrogen pentoxide (NO) in an atmospheric simulation chamber using a quantum cascade laser.

A spectroscopic instrument based on a mid-infrared external cavity quantum cascade laser (EC-QCL) was developed for high-accuracy measurements of dinitrogen pentoxide (NO) at the ppbv-level. A specific concentration retrieval algorithm was developed to remove, from the broadband absorption spectrum of NO, both etalon fringes resulting from the EC-QCL intrinsic structure and spectral interference lines of HO vapour absorption, which led to a significant improvement in measurement accuracy and detection sensitivity (by a factor of 10), compared to using a traditional algorithm for gas concentration retrieval. The developed EC-QCL-based NO sensing platform was evaluated by real-time tracking NO concentration in its most important nocturnal tropospheric chemical reaction of NO + NO ↔ NO in an atmospheric simulation chamber.

F/Yb-codoped sol-gel silica glasses: toward tailoring the refractive index for the achievement of high-power fiber lasers.

Accurate control of both the doping distribution inside the fiber core and the low refractive index contrast between the fiber core and cladding materials is essential for the development of high-power fiber lasers based on the use of single-mode large-mode-area (LMA) optical fibers. Herein, sol-gel monolithic F/Yb-codoped silica glasses were prepared from porous large silica xerogels doped with ytterbium salt solution, which had been subjected to fluorination with hexafluoroethane gas, before subsequent sintering. The fluorine content inside the doped glass has been varied by adjusting the fluorination duration.

Kinetic Study of the Gas-Phase Reactions of Nitrate Radicals with Methoxyphenol Compounds: Experimental and Theoretical Approaches.

The gas-phase reactions of five methoxyphenols (three disubstituted and two trisubstituted) with nitrate radicals were studied in an 8000 L atmospheric simulation chamber at atmospheric pressure and 294 ± 2 K. The NO3 rate constants were investigated with the relative kinetic method using PTR-ToF-MS and GC-FID to measure the concentrations of the organic compounds. The rate constants (in units of cm(3) molecule(-1) s(-1)) determined were: 2-methoxyphenol (guaiacol; 2-MP), k(2-MP) = (2.

Extreme large mode area in single-mode pixelated Bragg fiber.

This paper reports the design and the fabrication of an all-solid photonic bandgap fiber with core diameter larger than 100 µm, a record effective mode area of about 3700 µm at 1035 nm and robust single-mode behavior on propagation length as short as 90 cm. These properties are obtained by using a pixelated Bragg fiber geometry together with an heterostructuration of the cladding and the appropriated generalized half wave stack condition applied to the first three higher order modes. We detail the numerical study that permitted to select the most efficient cladding geometry and present the experimental results that validate our approach.

Polarization maintaining single-mode fiber delivering a flat top intensity profile.

We report, through numerical simulations and experimental data, the first successful fabrication of a polarization maintaining single-mode fiber delivering a flat top intensity profile at 1.05 µm. A high quality flat mode was obtained and single-mode behavior was checked by shifting the injection and by S² imaging method.

High-quality ultraviolet beam generation in multimode photonic crystal fiber through nondegenerate four-wave mixing at 532 nm.

All-fiber ultraviolet (UV) light sources are of great practical interest for a multitude of applications spanned across different sectors, from industrial processes such as nonthermal, high-resolution materials processing, to biomedical applications such as eye surgery, to name a few. However, production of UV light sources with high beam quality has been a problem to this day as the fiber designs required to reach UV wavelengths by four-wave mixing with widely available pumps (i.e.

Rate coefficients for the gas-phase reaction of chlorine atoms with a series of methoxylated aromatic compounds.

The reaction of a series of oxygenated aromatics (two methoxybenzene and six methoxyphenol isomers) with chlorine atoms has been studied in two simulation chambers with volumes of 1080 and 480 L at the University of Wuppertal. Experiments were performed at 295 ± 2 K and a total pressure of synthetic air of 1 bar using the relative kinetic method with in situ Fourier transform infrared spectroscopy for chemical analysis. The following rate coefficients (in units of cubic centimeter per molecule per second) were determined: (1.

Rate coefficients for the gas-phase reaction of hydroxyl radicals with 2-methoxyphenol (guaiacol) and related compounds.

2-Methoxyphenol (guaiacol) and its derivatives are potential marker compounds for wood smoke emissions in the atmosphere. To investigate the atmospheric reactivity of this type of compounds, rate coefficients for their reactions with hydroxyl (OH) radicals have been determined at 294 ± 2 K and 1 atm using the relative rate method with gas chromatography for chemical analysis. The rate coefficients (in units of cm³ molecule⁻¹ s⁻¹) are: 2-methoxyphenol, (7.

Unexpected multifunctional effects of methylated cyclodextrins in a palladium charcoal-catalyzed Suzuki-Miyaura reaction.

[reaction: see text] Native and modified cyclodextrins (CDs) have shown polyvalent properties in a biphasic Pd/C-catalyzed Suzuki-Miyaura reaction. In addition to their mass transfer ability, the CDs favored the dispersion of the catalyst in water. With the randomly methylated CDs (RaMe-beta-CD), the gains of initial activities were multiplied by factors between 3.