Enthalpy-Entropy Compensation Effect in Saturated Solutions on an Example of Polynuclear Aromatics According to Thermodynamics at Melting Temperature.

A thermodynamic the influence of temperature on the logarithm of the considered quantity is expressed by bifunctional functional terms (1/T, lnT). For this purpose, the Apelblat & Manzurola (A&M) equation was used for extended model dissolution analysis of 12 aromatic hydrocarbons in tetralin and decalin vs. temperature for saturated solutions.

Ni-Supported Pd Nanoparticles with Ca Promoter: A New Catalyst for Low-Temperature Ammonia Cracking.

In this paper we report a new nanometallic, self-activating catalyst, namely, Ni-supported Pd nanoparticles (PdNPs/Ni) for low temperature ammonia cracking, which was prepared using a novel approach involving the transfer of nanoparticles from the intermediate carrier, i.e. nano-spherical SiO2, to the target carrier technical grade Ni (t-Ni) or high purity Ni (p-Ni) grains.