Remarkably Stable Glassy GeS Densified at 8.3 GPa: Hidden Polyamorphism, Contrasting Optical Properties, Raman and DFT Studies, and Advanced Applications.

Glassy GeS, densified at 8.3 GPa, exhibits a strongly reduced bandgap, predominantly tetrahedral Ge environment, enhanced chemical disorder and partial 3-fold coordination of both germanium and sulfur, assuming two possible reaction paths under high pressure: (i) a simple dissociation 2Ge-S ⇄ Ge-Ge + S-S and (ii) a chemical disproportionation GeS ⇄ GeS + S. The observed electronic and structural changes remain intact for at least seven years under ambient conditions but are gradually evolving upon heating.

GeTe Phase Change Material for Terahertz Devices with Reconfigurable Functionalities Using Optical Activation.

The phenomenon of phase change transition has been a fascinating research subject over decades due to a possibility of dynamically controlled materials properties, allowing the creation of optical devices with unique features. The present paper unravels the optical characteristics and terahertz (THz) dielectric permittivity of a novel phase change material (PCM), GeTe, prepared by pulsed laser deposition (PLD) and their remarkable contrast in crystalline and amorphous states, in particular, a difference of 7 orders of magnitude in conductivity. The THz spectra were analyzed using the harmonic oscillator and Drude term.

Pressure-Driven Chemical Disorder in Glassy AsS up to 14.7 GPa, Postdensification Effects, and Applications in Materials Design.

A small difference in energy between homopolar and heteropolar bonds and the glass-forming ability of pure chalcogens leads to unexpected trends in densification mechanisms of glassy chalcogenides compared to vitreous oxides. Using high-precision compressibility measurements and in situ high-energy X-ray diffraction up to 14.7 GPa, we show a new densification route in a canonical glass AsS.

Bandgap guidance in hybrid chalcogenide-silica photonic crystal fibers.

We report a hybrid chalcogenide-silica photonic crystal fiber made by pressure-assisted melt-filling of molten glass. Photonic bandgap guidance is obtained at a silica core placed centrally in a hexagonal array of continuous centimeters-long chalcogenide strands with diameters of 1.45 μm.