Scaling of average power in sub-MW peak power Yb-doped tapered fiber picosecond pulse amplifiers.

Prospects for average power scaling of sub-MW output peak power picosecond fiber lasers by utilization of a Yb-doped tapered fiber at the final amplification stage were studied. In this paper, it was shown experimentally that a tapered fiber allows the achievement of an average power level of 150 W (limited by the available pump power) with a peak power of 0.74 MW for 22 ps pulses with no signs of transverse mode instability.

Optical gain and laser generation in bismuth-doped silica fibers free of other dopants.

Luminescence emission and excitation spectra of bismuth-doped silica optical fibers free of other dopants have been obtained to construct an emission-excitation map in a wide wavelength range of 400-1600 nm. The main low-lying energy levels of the bismuth active centers in such fibers have been determined. For the first time (to our knowledge), optical gain and lasing have been obtained in such fibers.

Nature of molecular rotation in supercooled glycerol under nanoconfinement.

The dynamics of glass-forming liquids under nanoconfinement is key to understanding a variety of phenomena in nature and modern technology. We report a (13)C NMR spectroscopic study that directly demonstrates that alpha-relaxation in bulk glycerol involves an isotropic rotational jump of the constituent molecules. The activation energy of this motion is approximately 78 kJ mol(-1) in the bulk, which abruptly changes to a low value of approximately 27.

Broadband wavelength conversion in a germanosilicate-core photonic crystal fiber.

A photonic crystal fiber with a germanosilicate core having a nonlinear coefficient of 40 (W km)(-1) near the single dispersion zero at 1.09 microm is fabricated and studied. Broadband parametric wavelength conversion of the Ti:sapphire laser output tunable at 0.

Inelastic neutron scattering study of confined surface water on rutile nanoparticles.

The vibrational density of states (VDOS) for water confined on the surface of rutile-TiO(2) nanoparticles has been extracted from low temperature inelastic neutron scattering spectra. Two rutile-TiO(2) nanoparticle samples that differ in their respective levels of hydration, namely TiO(2) x 0.37 H(2)O (1) and TiO(2) x 0.

Direct visualization of phase transition dynamics in binary supported phospholipid bilayers using imaging ellipsometry.

Via imaging ellipsometry, we study the phase transition dynamics induced by selective gelation of one component in a binary supported phopholipid bilayer. We find the modulation of two attendant morphological features: emergence of extended defect chains due to a net change in the molecular areas and fractal-like domains suggesting weak line tension. A time-lapse analysis of the ellipsometric images reveals the cluster size of 4-20 molecules undergoing gelation indicating weak cooperativity.

Dynamics of water confined on a TiO2 (anatase) surface.

Inelastic neutron scattering has been employed to probe the vibrational density of states of water confined by an oxide surface, namely, nanoparticles of the anatase polymorph of TiO2. The heat capacity of confined water has been measured by adiabatic calorimetry and compared with values derived from the vibrational density of states. Both inelastic neutron scattering and calorimetry demonstrate restricted mobility and lower heat capacity and entropy of confined water as compared to the bulk.

Interfacial effects on vitrification of confined glass-forming liquids.

Mesoporous silica phases, with uniform pores of dimensions in the 2-30 nm range, offer a uniquely well-defined environment for the study of the effects of two-dimensional spatial confinement on the properties of glass-forming liquids. We report observations by differential scanning calorimetry of the vitrification of o-terphenyl (OTP), salol, and glycerol in hexagonal mesoporous silica (MCM-41 and SBA-15) in a wide range of pore sizes from 2.6 to 26.