Publications by authors named "Andrew Kyriacou"

Naturally-sourced cellulose nanocrystals (CNCs) are elongated, birefringent nanoparticles that can undergo cholesteric self-assembly in water to produce vibrant, structurally colored films. As such, they are an ideal candidate for use as sustainable and cost-effective inks in the printing of scalable photonic coatings and bespoke patterns. However, the small volume and large surface area of a sessile CNC drop typically leads to rapid evaporation, resulting in microfilms with a coffee-stain-like morphology and very weak coloration.

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A series of potentially tetradentate and pentadentate ligands modelled on BPMEN has been prepared and their iron(II) bis(triflate) complexes have been isolated and characterised by spectroscopic and crystallographic techniques (BPMEN = N,N'-bis(pyridylmethyl)ethylenediamine). Changes to the BPMEN ligand have invariably led to complexes with different coordination modes or geometries and with inferior catalytic efficiencies for the oxidation of cyclohexane with H2O2. The reaction of an iron(II) complex containing a pentadentate BPMEN-type ligand with O2 has resulted in ligand degradation via oxidative N-dealkylation and the isolation of a bis(hydroxo)-bridged dinuclear iron(III) complex with a picolinate-type ligand.

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