Bioplastics have entered everyday life as a potential sustainable substitute for commodity plastics. However, still further progress should be made to clarify their degradation behavior under controlled and uncontrolled conditions. The wide array of biopolymers and commercial blends available make predicting the biodegradation degree and kinetics quite a complex issue that requires specific knowledge of the multiple factors affecting the degradation process.
View Article and Find Full Text PDFIn the present study commercial Polylactic Acid-based disposable cups and plates were selected for lab scale anaerobic degradability tests. The experiments were carried out under thermophilic conditions at different inoculum to substrate ratios and test material sizes, and the specific biogas production and associated kinetics were evaluated. Maximum biogas production was comparable for almost all the experimental runs (1620 and 1830 NmL/gTOC) and a biodegradation degree in the range 86-100% was attained.
View Article and Find Full Text PDFVolatile fatty acids (VFAs) are high-value chemicals that are increasingly demanded worldwide. Biological production via food waste (FW) dark fermentation (DF) is a promising option to achieve the sustainability and environmental benefits typical of biobased chemicals and concurrently manage large amounts of residues. DF has a great potential to play a central role in waste biorefineries due to its ability to hydrolyze and convert complex organic substrates into VFAs that can be used as building blocks for bioproducts, chemicals and fuels.
View Article and Find Full Text PDFCheese whey (CW) is the main by-product of the dairy industry and is often considered one of the main agro-industrial biowaste streams to handle, especially within the European Union, where the diary activities play an essential role in the agrarian economy. In the paper, Life Cycle Assessment (LCA) is used to analyse the feasibility of producing polyhydroxyalkanoates (PHA) as the main output of an innovative CW valorisation route which is benchmarked against a conventional anaerobic digestion (AD) process. To this aim, the LCA inventory data are derived from lab-scale PHA accumulation tests performed on real CW, while data from the literature of concern are used for modelling both the PHA extraction from the accumulating biomass and for the alternative CW valorisation through AD.
View Article and Find Full Text PDFThe Circular and Green Economy principles is inspiring new approaches to municipal wastewater treatment plants (MWWTPs) design and operation. Recently, an ever-growing interest is devoted to exploring the alternatives for switching the WWTPs from being able to 'simply' removing contaminants from water to biorefinery-like plants where energy and material can be recovered. In this perspective, both wastewater and residues from process can be valorised for recovering nutrients (N and P), producing value added products (i.
View Article and Find Full Text PDFAnaerobic digestion (AD) of organic waste, although widely practiced, may require suitable accompanying treatments to enhance the degradability of complex materials. Since these may require significant efforts in terms of energy and chemical demand, careful assessment of their overall environmental sustainability is mandatory to evaluate their full-scale feasibility. The study aims to represent the environmental profile of ultrasonication (US) applied as a post-treatment of anaerobic digestion of agro-industrial organic residues.
View Article and Find Full Text PDFWith an estimated worldwide production of 190 billion kg per year, and due to its high organic load, cheese whey represents a huge opportunity for bioenergy and biochemicals production. Several physical, chemical and biological processes have been proposed to valorise cheese whey by producing biofuels (methane, hydrogen, and ethanol), electric energy, and/or chemical commodities (carboxylic acids, proteins, and biopolymers). A biorefinery concept, in which several value-added products are obtained from cheese whey through a cascade of biotechnological processes, is an opportunity for increasing the product spectrum of dairy industries while allowing for sustainable management of the residual streams and reducing disposal costs for the final residues.
View Article and Find Full Text PDFThe concept of biorefinery expands the possibilities to extract value from organic matter in form of either bespoke crops or organic waste. The viability of biorefinery schemes depends on the recovery of higher-value chemicals with potential for a wide distribution and an untapped marketability. The feasibility of biorefining organic waste is enhanced by the fact that the biorefinery will typically receive a waste management fee for accepting organic waste.
View Article and Find Full Text PDFThis paper evaluates the effects of ultrasonication (US) applied, individually or in combination with a mechanical treatment, to the effluent of anaerobic digestion (AD) of lignocellulosic waste, on methane (CH) production. US of the substrate downstream of AD is a relatively novel concept aimed at improving the degradation of recalcitrant components in order to enhance the overall energy efficiency of the process. US tests were carried out on real digestate samples at different energies (500-50,000 kJ/kg total solids (TS), corresponding to sonication densities of 0.
View Article and Find Full Text PDFThree different experimental sets of runs involving batch fermentation assays were performed to evaluate the influence of the experimental conditions on biological hydrogen production from the source-separated organic fraction of municipal solid waste collected through a door-to-door system. The fermentation process was operated with and without automatic pH control, at a pH of 5.5 and 6.
View Article and Find Full Text PDFBatch factorial experiments were performed on cheese whey+wastewater sludge mixtures to evaluate the influence of pH and the inoculum-to-substrate ratio (ISR) on fermentative H production and build a related predictive model. ISR and pH affected H potential and rate, and the fermentation pathways. The specific H yield varied from 61 (ISR=0, pH=7.
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