Assessing Microplastics and Nanoparticles in the Surface Seawater of Venice Lagoon-Part I: Methodology of Research.

Microplastics (MPs) and nanoplastics (NPs) both represent significant concerns in environmental sciences. This paper aims to develop a convenient and efficient methodology for the detection and measurement of MPs and nanoparticles from surface seawater and to apply it to the water samples collected from the UNESCO site of Venice and its lagoon, more precisely in the Venice-Lido Port Inlet, Grand Canal under Rialto Bridge, and Saint Marc basin. In this study, MPs were analyzed through optical microscopy for their relative abundance and characterized based on their color, shape, and size classes, while the concentration and the mean of nanoparticles were estimated via the Nanoparticle Tracking Analysis technique.

ZnO nanostructured matrix as nexus catalysts for the removal of emerging pollutants.

Water pollution stands as a pressing global environmental concern, elevating the significance of innovative, dependable, and sustainable solutions. This study represents an extensive review of the use of photocatalytic zinc oxide nanoparticles (ZnO NPs) for the removal of emerging pollutants from water and wastewater. The study examines ZnO NPs' different preparation methods, including physical, chemical, and green synthesis, and emphasizes on advantages, disadvantages, preparation factors, and investigation methods for the structural and morphological properties.

Alternative Solid Activators from Waste Glass for One-Part Alkali-Activated Fly Ash/Red Mud Cements.

Solid activators based on waste glass for the manufacture of one-part alkali-activated fly ash/red mud materials were synthesized, characterized, and tested in this work. The synthesis was carried out via alkaline fusion with sodium hydroxide at different reaction temperatures and at different sodium hydroxide/waste glass mass ratios. The results showed that the reaction temperature decisively influences the properties of the obtained solid activators.

Insights into Anthropogenic Micro- and Nanoplastic Accumulation in Drinking Water Sources and Their Potential Effects on Human Health.

Anthropogenic microplastics (MPs) and nanoplastics (NPs) are ubiquitous pollutants found in aquatic, food, soil and air environments. Recently, drinking water for human consumption has been considered a significant pathway for ingestion of such plastic pollutants. Most of the analytical methods developed for detection and identification of MPs have been established for particles with sizes > 10 μm, but new analytical approaches are required to identify NPs below 1 μm.

Ferrous Industrial Wastes-Valuable Resources for Water and Wastewater Decontamination.

Ferrous waste by-products from the metallurgical industry have a high potential for valorization in the context of the circular economy, and can be converted to value-added products used in environmental remediation. This research reviews the latest data available in the literature with a focus on: (i) sources from which these types of iron-based wastes originate; (ii) the types of ferrous compounds that result from different industries; (iii) the different methods (with respect to the circular economy) used to convert them into products applied in water and wastewater decontamination; (iv) the harmful effects ferrous wastes can have on the environment and human health; and (v) the future perspectives for these types of waste.

Walnut Shell Biowaste Valorization via HTC Process for the Removal of Some Emerging Pharmaceutical Pollutants from Aqueous Solutions.

This research emphasizes the performance of some eco-friendly carbon materials as hydrochars (HC) obtained by the hydrothermal carbonization (HTC) process applied to walnut shell (WS) biowaste. These materials display promising properties that can be used for environmental applications such as emerging pharmaceutical pollutant retention from water sources. Thus, three hydrochars coded HCWS1, HCWS2, and HCWS3 were obtained using a dynamic autoclave in specific conditions-temperature of 220 °C, autogenous pressure, 1:10 biomass-water weight ratio-and for three different reaction times, 1 h, 6 h, and 12 h.

Bioactive Collagen Hydrolysate-Chitosan/Essential Oil Electrospun Nanofibers Designed for Medical Wound Dressings.

In this study, lemon balm ( L.) and dill ( L.) essential oils (EOs) were encapsulated into collagen hydrolysates extracted from bovine tendons and rabbit skins, both mixed with chitosan (CS) by using the coaxial electrospinning technique for potential wound dressing applications.

An Innovative Method of Converting Ferrous Mill Scale Wastes into Superparamagnetic Nanoadsorbents for Water Decontamination.

The need to recycle and develop nanomaterials from waste, and use them in environmental applications has become increasingly imperative in recent decades. A new method to convert the mill scale, a waste of the steel industry that contains large quantity of iron and low impurities into a nanoadsorbent that has the necessary properties to be used for water purification is presented. The mill scale waste was used as raw material for iron oxide nanopowder.

Sustainable Rabbit Skin Glue to Produce Bioactive Nanofibers for Nonactive Wound Dressings.

This paper assessed the collagen glue (Col) from rabbit skin for use as a raw material in combination with different water-based dispersants of antimicrobial agents such as ZnO NPs, TiO NPs doped with nitrogen and Ag NPs (TiO-N-Ag NPs), and chitosan (CS) for the production of biocompatible and antimicrobial nanofibers. The electrospun nanofibers were investigated by scanning electron microscopy (SEM), attenuated total reflectance in conjunction with Fourier-transform infrared spectroscopy (ATR-FT-IR) analyses and antioxidant activity. The biocompatibility of electrospun nanofibers was investigated on cell lines of mouse fibroblast NCTC ((clone L929) using MTT test assays.

Effect of Styrene-Diene Block Copolymers and Glass Bubbles on the Post-Consumer Recycled Polypropylene Properties.

The recycled polypropylene (rPP) materials that meet technical requirements such as reducing the dimensions and improving the tensile, elongation, impact strength, thermal stability, as well as melt processing, are required for the manufacturing industry. In this paper, we studied the mechanical and thermal properties of post-consumer rPP by adding both synthesized thermoplastic elastomers, and glass bubbles (GB) by a melt allowing process. Styrene-butadiene (SBS) and styrene-isoprene (SIS) block-copolymers that had a styrene content of 30 wt% were synthesized by anionic sequential polymerization.

Synthesis and characterization of dextran-coated iron oxide nanoparticles.

Synthesis and characterization of iron oxide nanoparticles coated with a large molar weight dextran for environmental applications are reported. The first experiments involved the synthesis of iron oxide nanoparticles which were coated with dextran at different concentrations. The synthesis was performed by a co-precipitation technique, while the coating of iron oxide nanoparticles was carried out in solution.