The paper investigates how polymer films are influenced by two different polymerization processes happening either simultaneously or one after the other, focusing on their anchoring properties.
It explains a compensating effect observed when using two orthogonal polymerization methods, detailing how the anchoring energy is calculated from changes in Helmholtz free energy in a defined interface layer.
The findings include a mathematical expression that accounts for the angular orientation of the photoaligning processes and proposes a method for achieving controlled anchoring strength during fabrication.