Titanium-Anchored Gold on Silica for Enhanced Catalytic Activity in Aqueous Ethanol Oxidation.

The heterogeneously catalyzed oxidation of bioethanol offers a promising route to bio-based acetic acid. Here, we assess an alternative method to support gold nanoparticles, which aims to improve selectivity to acetic acid through minimizing over-oxidation to carbon dioxide. The most promising support system is 5 wt % titanium on silica, which combines the high surface area of silica with the stabilizing effect of titania on the gold particles.